150. The nido-Cage···pBond: A Non-covalent Interaction between Boron Clusters and Aromatic Rings and 

Its ApplicationsAngew. Chem. Int. Ed. 2020, 59, 9018.

149. MetalFree Oxidative B−N Coupling of nidoCarborane with NHeterocycles,Angew. Chem. Int. Ed., 2019, 58, 11886


148.BoronClusterEnhanced Ultralong Organic Phosphorescence, Angew. Chem. Int. Ed., 2019, 58, 9129


147.AggregationInduced Electrochemiluminescence of Carboranyl Carbazoles in Aqueous Media, Angew. Chem. Int. Ed., 2019, 58, 3162


146. Description of an Unusual Hydrogen Bond between Carborane and a Phenyl Group, Wenli Zou,  Xiaolei Zhang, Humin Dai, Hong Yan,* Dieter Cremer and Elfi Kraka *, J. Organomet. Chem. Accepted.


145.S.V. Timofeev, O.B. Zhidkova, I.B. Sivaev, Z.A. Starikova, K.Yu. Suponitsky, H. Yan*, V.I. Bregadze*, Synthesis of rhodacarboranes containing σ- and π-carboranyl ligands in one molecule, J. Organomet. Chem., doi: 10.1016/j.jorganchem.2017.11.014


144. Transition Metal-induced B–H Functionalization of o-Carborane, Xiaolei Zhang, Hong Yan*, Coord. Chem. Rev. 2017, online.


143.Pyridyl Directed Cp*Rh(III) Catalyzed B(3)–H Acyloxylation of o-Carborane, Chun-Xiao Li, Hao-Yun Zhang, Tsz-Yung Wong, Hou-Ji Cao, Hong Yan*, Chang-Sheng Lu*, Org. Lett. 2017, 19, 5178-5181.


142. A novel phosphorescent iridium(III) complex bearing donor-acceptor-type o-carboranylated ligand for endocellular hypoxia imagingXiang Li, Yongheng Yin, Hong Yan,* Changsheng Lu,* and Qiang Zhao*Dalton Trans.2017, 46, 13802 – 13810.


141. Reactivity of Half-Sandwich 16 Electron Compound CpCo(S2C2B10H10) with Ethyl Diazoacetate and Allenes, Gui-Feng Liu,  Hong Yan, Chinese J. of Inorg. Chem.  2017, 33, 487-492.   


140. Highly-Emissive Organic Single-Molecule White Emitters by Engineering o-Carborane-based Luminophores, Deshuang Tu, Pakkin Leong, Song Guo, Hong Yan,* Changsheng Lu* and Qiang Zhao*,  Angew. Chem. Int. Ed. 2017, 56(38), 11370-11374.


139. Pd(II)-Catalyzed Synthese of Benzyl Benzoates via Benzyl C(sp3)−H Activation, Dan-dan Duanmu, Pak-kin Leong, Qi-bai Jiang, * and Hong Yan,* Chinese J. of Org. Chem.2017, 37, 2669-2677.


138. Progress in Selective B-H Bond Functionalization of Carborane, Huanhuan Li, Hong Yan*, Changsheng Lu*, Chinese J. Inorg. Chem.2017, 33, 1313-1329.


137. Base–Promoted Decarboxylative Azo–Coupling: Construction of Unsymmetrical Azocarboranes  

Huan–huan Li, Fan Bai, Hong Yan* and Chang–sheng Lu*, Org. Lett.2017, 19, 862-865.


136. Iridium(III)–Catalyzed Selective Sulfonamidation of o–Carborane with Sulfonyl Azides via Carboxylic Acid–Assisted B (4)–H Bond Activation, Huanhuan Li,  Fan Bai,  Hong Yan* and Changsheng Lu*, Vladimir, I, Bregadze*,  Eur. J. Org. Chem. 2017, 1343–1352.


135. Selective Catalytic B−H Arylation of o‑Carboanyl Aldehydes by a Transient Directing Strategy, Xiaolei Zhang,* Hongning Zheng, Jie Li, Fei Xu, Jing Zhao, and Hong Yan*,J. Am. Chem. Soc. 2017,139, 14511-14517.

134. Novel phosphorescent cationic iridium(III) complexes with o- carboranylation on the ancillary N^N ligand, Xiang Li,  Yongheng Yin, Hong Yan,* Changsheng Lu,* and Qiang Zhao*, Dalton Trans. 2017, 46, 10082–10089.

133. Aggregation–induced emission characteristics of o-carborane-functionalized tetraphenylethylene luminogens: the influence of carborane cages on photoluminescence, Xiang Li,  Yongheng Yin,  Hong Yan*, and Changsheng Lu*, Chem.Asian J. 2017, 12, 2207–2210.


132. Using highly emissive and environmentally sensitive o-carborane-functionalized metallophosphors to monitor mitochondrial polarity , Xiang Li, Xiao Tong, Yongheng Yin, Hong Yan,* Changsheng Lu,* Wei Huang, and Qiang Zhao*, Chem. Sci.2017, 8, 5930 –5940.


131. Carborane derivative conjugated with gold nanoclusters for target cancer cell imaging, Jianling Wang, Leifeng Chen, Jing Ye, Zhiyong Li, Hui Jiang, Hong Yan*, Marina Y. Stogniy, Igor Sivaev, Vladimir I. Bregadze and Xuemei Wang*, Biomacromolecules 2017, 18,1466-1472.

130. A Highly Potent Antibacterial Agent Targeting Methicillin-Resistant Staphylococcus aureus Based on Cobalt Bis(1,2-Dicarbollide) Alkoxy Derivative, Youkun Zheng, Weiwei Liu, Yun Chen, Hui Jiang, Hong Yan, Irina Kosenko, Lubov Chekulaeva, Igor Sivaev, Vladimir Bregadze, and Xuemei Wang*, Organometallics2017, 36, 3484-3490.


129. Copper(II) Catalyzed Domino Synthesis of Quinoline Derivatives from Arylamines and Alkynes,

Huimin Dai, Zihao Wang, Chao Yu and Hong Yan*, Changsheng Lu*, Org. Chem. Front.2017,  4, 2008 – 2011.


128. Chiral Ruthenium(II) Complexes as Supramolecular Building Blocks for Heterometallic Self-Assembly, Iranmanesh, Hasti; Arachchige, Kasun; Bhadbhade, Mohan; Donald, William; Liew, Jane; Liu, Kenny; Luis, Ena; Moore, Evan; Price, Jason; Yan, Hong; Yang, Jiajia; Beves, Jonathon*, Inorg. Chem.2016, 55 (24), 2737-12751.


127. Carborane-incorporated mononuclear Co(II) complex showing zero-field slow magnetic relaxation, Deshuang Tu, Dong Shao, Hong Yan* and Changsheng Lu*,Chem. Commun.2016, 52, 14326 – 14329.


126. A Convenient Approach to Synthesize o–Carborane Functionalized Phosphorescent Iridium(III) Complexes for Endocellular Hypoxia Imaging, Xiang Li, Xiao Tang, Hong Yan,* Changsheng Lu,*  Qiang Zhao,* and Wei Huang,Chem. Eur. J.  2016, 22, 17282-17290.


125. Carborane-Triggered Metastable Charge Transfer State Leading to Spontaneous Recovery of Mechanochromic Luminescence, Deshuang Tu, Pakkin Leong, Zhihong Li, Rongrong Hu, Chao Shi, Kenneth Yin Zhang,  Hong Yan,* and Qiang Zhao*,Chem. Commun. 2016, 52, 12494-12497.


124.Visible Light-Induced Cascade Reaction of Isocyanides and N-Arylacrylamides with Diphenylphosphine Oxide via Radical C−P and C−C Bond Formation, Chun-Xiao Li, De-Shuang Tu, Rui Yao, Hong Yan,* and Chang-Sheng Lu*, Org. Lett. 2016, 18, 4928-4931.


123. Solvent-Controlled , Tunable β-OAc and β-H Elimination in Rh(III)-Catalyzed Allyl Acetate and Aryl Amide Coupling via C-H Activation,  Huimin Dai, Zihao Wang, Chao Yu, Hong Yan* and Changsheng Lu*,Org. Lett. 2016,2016, 18, 3410-3413.


122. Pyrrolylmethyl Functionalized o-Carborane Derivatives, Huimin Dai, Guifeng Liu, Xiaolei Zhang, Hong Yan* and Changsheng Lu*, Organometallics 2016, 35, 1488-1496.

121. Rh(III)-catalyzed C–H allylation of amides and domino cycling synthesis of 3,4-dihydroisoquinolin-1(2H)-ones with NBS, Huimin Dai, Chao Yu, Changsheng Lu and Hong Yan*, Eur. J. Org. Chem.2016, 7,1255-1259.

120. B−H···π Interactions: A New Type of Nonclassical H-Bonding, Xiaolei Zhang, Huimin Dai, Hong Yan*, Wenli Zou, Dieter Cremer*, J. Am. Chem. Soc. 2016, 138, 4334-4337.

119. Carboranes as a Tool to Tune Phosphorescence, Xiang Li, H. Yan,* and Qiang Zhao*,Chem. Eur. J.  2016, 22, 1888-1898.


118. Badly behaving bipyridine: the surprising coordination behaviour of 5,5-substituted-2,2-bipyridine towards iron(II) and ruthenium(II) ions, H. Iranmanesh, M. Bhadbhade, N. D. Haas, E. T. Luis, H. Yan, J. J. Yang, and J. E. Beves*, Supramolecular Chem.2015, 27, 854-864.


117. Cobalt-promoted B–H and C–H activation in the three-component reactions of 16-electron cobalt carboranedithiolate, alkyne and bronsted acids, R. Zhang, L. Zhu, Z. Z. Lu, H. Yan*, J. Organomet. Chem.2015, 798, 152-159.


116. Cobalt(III)-mediated intramolecular coupling of B(3)/B(6) in CpCoS2C2B10H10 with Cp ligand, Hongde Ye, Baohua Xu, Jiurong Hu, Hong Yan*, Chinese J. Inorg. Chem.2015, 31, 1447-1452.


115.Reactivity of unsaturated 16e half-sandwich complex Cp*Ir(S2C2B10H10) with ortho-and meta-substituted phenyl azides, Wei Zhong and Hong Yan*, Chinese J. Inorg. Chem.2015, 31,1305-1314. (front cover)


114. Self-assembled supramolecular cages containing ruthenium(II) polypyridyl complexes, Jiajia Yang, Mohan Bhadbhade,  William A. Donald, Hasti Iranmanesh, Evan G. Moore, Hong Yan and Jonathon E. Beves*, Chem. Commun.  2015, 51, 4465-4468.


113. Effective Nitration of Anilides and Acrylamides by tert-Butyl Nitrite, Yi-fei Ji, Hong Yan*, and Qi-bai Jiang*,  Eur. J. Org. Chem.  2015, 9, 2051-2060.


112.Droplet Electrochemical Study of the pH Dependent Redox Behavior of Novel Ferrocenyl-Carborane Derivatives and Its Application in Specific Cancer Cell Recognition, Changyu Wu; Afzal Shah; Hongde Ye; Xiao Chen; Jing Ye; Hui Jiang; Baoan Chen; Xuemei Wang; Hong Yan, Anal. Chim. Acta,2015, 857, 39-45.


111. Tuning Optical Properties of 2-Thienylpyridyl Iridium Complexes by Carborane and Anion, Lin Zhu, Xiao Tang,Qi Yu, Wen Lv, Hong Yan,* Qiang Zhao,*and Wei Huang*, Chem. Eur. J.2015, 21, 4721-4730.


110. Metal-induced B–H Activation in the Three-component Reactions: 16-Electron Complex CpCo(S2C2B10H10), Ethyl diazoacetate and Alkynes, Guifeng Liu and Hong Yan*,Organometallics,2015, 34, 591-598.


109. Synthesis of A Paramagnetic Carborane Derivative Containing A Furyl Ring and Its Formation Mechanism, Ye Hong-De, Li Xiang, Hu Jiu-Rong, Peng Hua-Nan, Hu Xin, Yan Hong, Chinese J.  Inorg. Chem.2014, 30, 1469-1473.


108.  Reactivity of 16-electron complexes Cp#Co(S2C2B10H10) (Cp# = Cp, Cp*) towards methyl diazoacetate and toluenesulphonyl azide , Wei Zhong, Mingshi Xie, Yizhi Li and Hong Yan*,RSC Adv., 2014, 4, 61799 - 61808 (advance article)


107.Carborane tuning phosphorescence of iridium tetrazolate complexes, Chao Shi, Deshuang Tu, Qi Yu, Hua Liang, Yahong Liu, Zhihong Li, Hong Yan,* Qiang Zhao,* and Wei Huang*, Chem. Eur. J. 2014, 20, 16550-16557.(hot paper)


106.MetalMetal Redox Synergy in Selective BH Activation of ortho-Carborane-9,12-dithiolateXiaolei Zhang, Zhiwen Zhou, Hong Yan*, Chem. Commun.2014, 50, 13077-13080.


105. Synthesis of Boron-fused 1,4-Dithiin via Cobalt-Mediated Disulfuration of Alkyne at 9, 12-o-Carborane-dithiolate Unit, Xiaolei Zhang, Zhiweng Zhou, Xiaodong Zou, and Hong Yan*, Organometallics, 2014, 33, 2661-2665.


104. Reactivity of Cp*M (M = Co, Rh, Ir) half-sandwich complexes containing a chelating 1, 2-dicarba-closo-dodecaborane-1,2-dichalcogenolato ligand with organic azides, Wei Zhong, Hong Yan*, Yizhi Li and Vladimir Bregadze*, Russ. Chem. Bull. 2014, 63, 953-962.


103. Radical coupling for directed C–C/C–S bond formation in the reaction of Cp*IrS2C2B10H10 with 1-azido-3-nitrobenzene, Wei Zhong,Qibai Jiang,Qian Zhang, Yi Shang, Hong Yan* and Vladimir Bregadze*, Dalton Trans. 2014, 43, 4962-4968


102. Multi-Pyridine Decorated Fe(II) and Ru(II) complexes by Pd(0)-Catalysed Cross Couplings: New Building Blocks for Metallosupramolecular Assemblies,  Jiajia Yang, Jack K. Clegg, Qibai Jiang, Xiaoming Liu, Hong Yan, Wei Zhong, Jonathon E. Beves, Dalton Trans., 2013, 42, 15625-15636.


101.Variable photophysical properties of Iridium(III) complexes triggered by closo- and nido-carborane substitution, Shi, C. Sun, H. B.Tang, X.Lv, W. Hong Yan.Zhao, Q. Wang, J. X. Huang, W.,Angew. Chem. Int. Ed.2013, 52, 13434-13438.


100.Carborane-Based Starburst Organic Fluorophores with Enhanced Two-Photon Absorption for Fluorescence Microscopy Imaging, Lin Zhu, Wen Lv, Shujuan Liu, Shengli Li,Hong Yan,* Qiang Zhao,* Wei Huang,*Chem. Commun.2013, 49, 10638-10640.


99. Unprecedented Boron-functionalized Carborane Derivatives by Facile and Selective Cobalt-induced B-H Activation, Zhaojin Wang, Hongde Ye, Yuguang Li, Yizhi Li and Hong Yan*, J. Am. Chem. Soc.2013,135, 11289-11298.


98. Synthesis and Characterization of Ni(II) and Ir(I) Complex with o-Carborane [O,P] or [O,O] Ligand,  Jiang Qi-Bai; Ji Yi-Fei; Shen Xu-Jie, Hong Yan, Chinese J. Inorg. Chem. 2013, 29, 910-914.


97. Reactivity of Dinuclear Ruthenium Complex Containing One μ-Se2 Unit and Two 1,2-Dicarba-closo-dodecaborane-1,2-dithiolate Ligands toward (cyclo-C6H10)(OH)C≡CH, Jiurong Hu*,  Huanan Peng, Xin Hu, Hongde Ye and  Hong Yan*, Acta Chimica Sinica, 2013,71, 892-896.


96. Reactivity of the 16-Electron CpCo Half-Sandwich Complex Containing a B(3,6)-Disubstituted o-Carborane-1,2-dithiolate Ligand, Xiao Tang, Zhaojin Wang, Yizhi Li, Hong Yan*,Vladimir I. Bregadze*, J. Organomet. Chem. 2013, 747, 90-97.


95. Boron-substituted o-carborane-trithiol to construct trimeric cobalt clusters, Xiaolei Zhang, Xiao Tang, Jiajia Yang, Yizhi Li, Hong Yan* andVladimir I. Bregadze*, Organometallics 2013, 32, 2014-2018.


94. Heterolytic H2 Splitting across a Ru–S Bond Leading to the Replacement of S by O in the Carborane-dithiolato Ligand of a 15-electron Ru(III) Complex, Qibai Jiang, Zhaojin Wang, Yizhi Li and Hong Yan*, Chem. Commun. 2013, 49, 5880-5882.


93.Carborane tuning photophysical properties of phosphorescent iridium(III) complexes,Chao Shi,Huibin Sun,Qibai Jiang,Qiang Zhao,* Jingxia Wang, Wei Huang,* and Hong Yan*, Chem. Commun. 2013, 49, 4746-4748. (back cover).




91. (p-cymene)Ru体系中选择性碳硼烷B-位点功能化叶红德吴德洪李玉广燕红*中国科技论文A201301-1369.


90. Amino-Directed Rh(III)-Catalyzed C–H Activation Leading to One-Pot Synthesis of N–H Carbazoles Q. B. Jiang, D. D. Duan-Mu, W. Zhong, H. Chen,* and H. Yan*, Chem. Eur. J. 2013, 19, 1903-1907.


89.New strategy for reversing biofilm-associatedantibiotic resistancethrough ferrocene-substituted carborane ruthenium(II)-arene complex, S. H. Li, C. Y. Wu, X. Tang, S. P. Gao, X. Q Zhao, H. Yan and X. M. Wang*,Science China-Chemistry,2013, 56, 595-603.


88.Antimicrobial activity of a ferrocene-substituted carborane derivative targeting multidrug-resistant infection, S. H. Li, Z. J. Wang, Y. F. Wei, C. Y. Wu, S. P. Gao, H. Jiang, X. Q. Zhao, H. Yan, X. M. Wang*,Biomaterials,2013, 34, 902-911.


87. Study on interaction between new carborane derivatives and Mb&Hb proteins, C. H. Wu, H. D. Ye, D. H. Wu, H. Yan, X. M. Wang*, J. Chen, Spectroscopy and spectroscopic analysis, 2013, 33, 120-125.


86. Discovery of ferrocene-carborane derivatives as novel chemical antimicrobial agents against multidrug-resistant bacteria, S. H. Li, C, Y. Wu, X. Y. Lv, X. Tang, X. Q. Zhao, H. Yan, H. Jiang and X. M. Wang*,  Science China-Chemistry,2012, 55, 2388-2395.


85. Synergistic antibacterial activity of new isomeric carborane derivatives through combination withnanoscaled titania, S. H. Li, C. Y. Wu, X. Q. Zhao, H. Jiang, H. Yan and X. M. Wang*, J Biomed Nanotechnol.2012, 9,393-402.


84.Synthesis and Reactivity of the Imido-Bridged Metallothiocarboranes CpCo(S2C2B10H10)(NSO2R)

W. Zhong, Q. W. Yang,Y. Shang,G. F. Liu, H. T. Zhao,*Y. Z. Liand H. Yan*, Organometallics, 2012, 31, 6658-6668.


83.Reactivity of 16-electron Half-sandwich Cobalt Compounds Containing a Chelating 1,2-Dicarba-closo-dodecaborane-1,2- dithiolate Ligand towards Methyl Propiolate and Dithio Ligands,

R. Zhang, L. Zhu, Z. Z. Lu, H. Yan* and V. I. Bregadze*, Dalton Trans.2012, 41, 12054-12063.


82. Reactivity of the half-sandwich 16e compound CpCo(S2C2B10H10) with ethynylferrocene in methanol, H. D. Ye, W. J. Bai, D. G. Zheng, J. R. Hu, H. N. Peng, H. Yan, Chinese J. Inorg. Chem.2012, 28, 1535-1540.


81. Cobalt-promoted B-H and C-H activation: Facile B-C coupling of carboranedithiolate and cyclopentadieneyl , R. Zhang,L. Zhu, G. F. Liu, H. M. Dai, Z. Z. Lu, J. B. Zhao and H. Yan*, J. Am. Chem. Soc. 2012, 134, 10341-10344.


80. Synthesis, cytotoxic activities and cell cycle arrest profiles of half-sandwich N-sulfonamide based dithio-o-carboranemetal complexes, H. Dou, W. Zhong, Y. Y.  Hou*, H. Yan*, Bioorg.& Med. Chem. 2012, 20, 4693-4700.


79.Mixed-Valent Diruthenium Half-sandwich Complex Containing Two Chelating 1,2-Dicarba-closo-dodecaborane-1,2-dithiolate Ligands: Reactivity towards (cyclo-C6H10)(OH)C≡CH and PhC(O)C≡CH, J. R.Hu, G. F. Liu, Q. B. Jiang, D. D. Duanmu,Y. Z. Li andH. Yan, J. Organomet. Chem.2012, 721-722, 36-41.


78.Unusual Group Migration and C(sp3)–H Activation Leading to Stable Metallacycles in the Reactions of Cp*IrS2C2B10H10 and Aryl Azides, W. Zhong, M. S. Xie, Y. Z. Li, H. Yan*, Chem. Commun.2012, 48, 2152-2154. (Advance Article)


77.Study on Specific Interaction of New Ferrocene-Substituted Carborane Conjugates with Hemoglobin Protein, C. H Wu, H. D. Ye, H. Jiang, X. M. Wang,* and H. Yan*, Science China—Chemistry,  2012, 55, 594-603.


76.New Strategy of Efficient Inhibition of Cancer Cells by Carborane Carboxylic Acid-CdTe Nanocomposites, C. H. Wu, L. X. Shi, Q, N. Li, H. Jiang, M. Selke, H. Yan, and X. M. Wang,*Nanomedicine,  2012, 8, 860-869.


75.Reactivity of the 16 Electron CpCoversus Cp*Co Half-sandwich Complex Containing an ortho-Carborane-1,2-dithiolate Ligand towards Ethynylferrocene, W. J. Bai, G. F. Liu, G. Guoyiqibayi, H. Yan*, Organometallics, 2011, 30, 5188-5195.


74.Selective Stepwise Substitutions in the B(3,6) Positions of the 16e Half-sandwich Complex CpCoS2C2B10H10, H. D. Ye, Q. B. Jiang, M. S. Xie, G. Y. Ding, Y. Z. Li,H. Yan*, Chinese J. Inorg. Chem.  2011, 27, 1601-1606.


73. Reactivity of the 16e CpCo Half-sandwich Complex Containing a Chelating 1,2-Dicarba-closo-dodecaborane-1,2-dithiolate Ligand towards Diynes, Z. W. Xu, H. Lei, Z. Z. Yang, X. J. Shen, H. Yan*, Chinese J. Inorg. Chem.2011, 27, 1669-1674.


72.  Reactivity of the 16e (p-cymene)Ru Half-sandwich Complex Containing a Chelating 1,2-Dicarba-closo-dodecaborane-1,2- dithiolate Ligand towards Diynes, Z. W. Xu, L. Han, C. Ji, R. Zhang, X. J. Shen and H. Yan*, Dalton Trans. 2011, 40, 6992-6997.(Advance Article)


71. Disulfuration and Hydrosulfuration of Alkyne at 1,2-Dicarba-closo-dodecaborane-thiolate Ligand, H. D. Ye,B. H. Xu, M. S. Xie,Y. Z. Li and H. Yan*, Dalton Trans.2011, 40, 6541-6546.(Advance Article)


70.  Reactivity of the 16electronCpCo Half-sandwich Complex Containing a Chelating 1,2-Dicarba-closo-dodecaborane-1,2- diselenolate Ligand towards FcC(O)C≡CH, H. D. Ye, W. J. Bai, M. S. Xie, Y. Z. Li, H. Yan*,  Eur. J. Inorg. Chem. 2011, 2011, 2763-2768.


69.  Cobalt–Mediated Selective B–H Activation and Formation of Co–B Bond in the Reaction of the 16 electron CpCo Half-sandwich Complex Containing an o-Carborane-1,2-dithiolate Ligand with Ethyl diazoacetate, G. F. Liu,J. R.Hu, J. L. Wen, H. M. Dai, Y. Z. Li and H. Yan*, Inorg. Chem. 2011, 50, 4187-4194.


68. Nanoscaled carborane ruthenium(II)-arene complex inducing lung cancer cells apoptosis, G. Zheng, C. H. Wu, H. D. Ye, H. Yan, X. M. Wang*, J. Nanobiotechnology, 2011, 9, 1-8.


67.  Multinuclear Self-assembly via a(p-Cymene)ruthenium Unit and an ortho-Carborane Selenolate Ligand J. R.Hu, J. L. Wen, D. H. Wu, R. Zhang, G. F. Liu, Q. B. Jiang, Y. Z. Li andH. Yan*, Organometallics, 2011, 30, 298-304.


66. Controlled Assembly of Ruthenium Complexes through ortho-Carborane Dithiolate and Polysulfide Ligands, J. R.Hu, G. F. Liu, Q. B. Jiang, R. Zhang, W.Huang andH. Yan*, Inorg. Chem. 2010, 49, 11199-11206.


65.Reactivity of the 16e Cp*Co Half-sandwich Complex Containing a Chelating 1,2-Dicarba-closo-dodecaborane-1,2-dithiolate Ligand toward Alkynes, H. D. Ye,  G. Y. Ding,M. S. Xie,Y. Z. Li and H. Yan*, Dalton Trans. 2011, 40, 2306-2313(Advance Article)


64. New Potential Anticancer Agent of Carborane Derivatives: Selective Cellular Interaction and Activity of Ferrocene-Substituted Dithio-o-carborane Conjugates, C. H. Wu, H. D. Ye, W. J. Bai, Q. N.  Li, D. D. Guo, G. Lv, H. Yan*, X. M. Wang*, Bioconjugate Chem. 2011, 22, 16-25.


63. Bioactivity of the Conjugation of Green-emitting CdTe Quantum Dots with a Carborane Complex, C. H. Wu, L. X. Shi, Q. N. Li, J. Zhao, M. Selke, H. Yan, X. M. Wang*, J. Nanoscience and Nanotechnology,2011, 11, 3091-3099.


62.Ferrocene-Substituted Dithio-o-Carborane Isomers: Influence on the Native Conformationof Myoglobin Protein, C. H. Wu, B. H. Xu, J. Zhao,Q. B.Jiang,F. D. Wei,H. Jiang, X. M. Wang,*and H. Yan*, Chem. Eur. J. 2010, 16, 8914-8922.


61. Reactions of a 16e Cp*Co Half-sandwich Complex Containing a Chelating 1,2-Dicarba-closo-dodecaborane-1,2-dithiolate Ligand with Alkynones HCºC–C(O)R (R = OMe, Me, Ph), Y. G. Li,  H. D.Ye, G. Guoyiqibayi, Q. B.Jiang, Y. Z.  Li, H. Yan*,Science China-Chemistry2010, 53, 2129-2138.


60.Ligand-to-metal Ratio Controlled Assembly of Cobalt Complexes Containing ortho-Carborane-thiolato and Butyl-thiolato Ligands, Y. G. Li, Q. B. Jiang, Y. Z. Li, X. J. Shen, H. Yan*, andV. I. Bregadze*, Inorg. Chem.2010, 49, 5584-5590.


59. Stepwise and Selective Carborane Substitution in the B(3,6) Positions of a 16e CpCo Half-sandwich Complex Containing a Chelating ortho-Carborane-1,2-dithiolate Ligand, Y. G. Li, Q. B. Jiang, X. L. Zhang, Y. Z. Li, H. Yan*, andV. I. Bregadze*, Inorg. Chem.2010, 49, 3911-3917.


58.Recent Development on Organometallic Chemistry Containing Carborane Ligand , G. Guoyiqibayi, Z. Rui,Y. Hong*, Chinese J. Inorg. Chem.2010, 26, 733-743.


57. Cobalt-mediated BH activation and cyclopentadienyl participated Diels-Alder addition in the reaction of a 16e CpCo complex containing an ortho-carborane-1,2-dithiolato  ligand with HCºC-C(O)Ph, Y. G. Li, Q. B. Jiang, Y. Z. Li, H. Yan* and V. I. Bregadze*,  Inorg. Chem.2010, 49, 4-6.


56. Syntheses and Structural  Characterization of Four New Siliver (I) Complexes  with the N, N’(O)-bidentate Bridging Ligands, Y. G. Li, Q. B. Jiang, K. Cheng, H. Yan, H. L. Zhu*, Z. Anorg. Allg. Chem.2009, 235, 2572-2578.


55. Ligand-Based Neutral Ruthenium(II) Arene Complexes: Selective Anticancer Action, C. H. Wu, D. H. Wu, X. Liu, G. Guoyiqibayi, D. D. Guo, G. Lv, X. M. Wang*, H. Yan*, H. Jiang, Z. H. Lu,  Inorg. Chem.2009, 49, 2352-2354.


54. Addition of ethynylferrocene to transition-metal complexes containing a chelating 1,2-dicarba-closo-dodecaborane-1,2-dichalcogenolate ligand---in vitro cooperativity of a ruthenium compound on cellular uptake of an anticancer drug, D. H. Wu, C. H. Wu,  Y. Z. Li, D. D. Guo, G. Lv, B. N. Chen, X. M. Wang* and H. Yan*,Dalton Trans.2009,38,285-290.


53. Reactions of 16e CpCo Half-Sandwich Complexes Containing a Chelating 1,2-Dicarba-closo-dodecaborane- 1,2-dichalcogenolate Ligand with Ethynylferrocene and Dimethyl Acetylene-dicarboxylate, B. H. Xu, X. Q. Peng, Y. Z. Li and H. Yan*, Chem. Eur. J.2008, 14, 9347-9356.


52. Cobalt(III)-Mediated Disulfuration and Hydrosulfuration of Alkynes, B. H. Xu, X. Q. Peng, Z. W. Xu, Y. Z. Li, and H. Yan*,  Inorg. Chem.2008, 47, 7928-7933.


51.Mixed-Valent Diruthenium Half-Sandwich Complexes Containing Two Chelating 1,2-Dicarba-closo-dodecaborane-1,2-dithiolate Ligands: Reactivity towards Phenylacetylene, 1,4-Diethynylbenzene and Ethynylferrocene, D. H. Wu, Y. G. Li, L. Han, Y. Z. Li, and H. Yan*, Inorg. Chem.2008, 47, 6524-6531.


50. Metal-Induced B-H Bond Activation: Addition of Methyl Acetylene Monocarboxylate to CpCo Half-Sandwich Complexes Containing a Chelating 1,2-Dicarba-closo-dodecaborane-1,2-dichalcogenolate Ligand, B. H. Xu, J. C. Tao, Y. Z, Li, S. H. Li*,  H. Yan*, Organometallics,2008, 27, 334-340.


49. Diruthenium Half-Sandwich Complexes Containing One í-E2 (E)S, Se) Unit and Two Chelating

1,2-Dicarba-closo-dodecaborane-1,2-dithiolate Ligands: Reactivity Studies with Methyl Acetylene Carboxylates, D. H. Wu, B. H. Xu, Y. Z. Li, and H. Yan*, Organometallics, 2007, 26, 6300-6306.


48. Reactivity of CpCo 16e Half-Sandwich Complexes Containing a Chelating 1,2-Dicarba-closo-dodecaborane-1,2-dichalcogenolate Ligand toward Phenylacetylene, B. H. Xu, D. H. Wu, Y. Z. Li, and H. Yan*, Organometallics,2007, 26, 4344-4349.


47.Synthesis, spectroscopic characterization, axial base coordination equilibrium and photolytic kinetics studies of a new coenzyme B12 analogue -  3’-deoxy-2’,3’-anhydrothymidylcobalamin

X. Zhang, X. J. Shen, H. Yan* and H. L. Chen*, J. C. S., Dalton Trans. 2007, 36, 2336-2342.


46. Transition metal complexes (M = Cu, Ni and Mn) of Schiff-base ligands: Syntheses, crystal structures, and inhibitorybioactivities against urease and xanthine oxidase, Y. G. Li, D. H. Shi, H. L. Zhu*, H. Yan, S. W. Ng, Inorg. Chim. Acta, 2007,360, 2881-2889.


45. A novel dinuclear ruthenium(I)/ruthenium(III) half-sandwich complex containing two chelating 1,2-dicarba-closo-dodecaborane-1,2-dichalocogenolate ligands and its reactivity with alkynes, D. H. Wu, C. Ji, Y. Z. Li and H. Yan*, Organometallics, 2007, 26, 1560-1562.


44. A newb-CD inclusion complex with a seven-membered ring bridged organocobaloxime, X. Zhang, Y. Z. Li, H. Yan, J. Hu, H. L. Chen*,  Inorg. Chem. Commun. 2006, 9, 907-910.


43. Reaction of nido-1,2-(Cp*RuH)2B3H7 with ethynylferrocene to yield new metallacarboranes, H. Yan*, B. C. Noll, T. P. Fehlner, J. Organomet. Chem.2006, 691, 5060-5064.


42. Cooperative metal-boron interactions  in the reaction of 1,2-nido-(Cp*RuH)2B3H7, Cp*=h5-C5Me5  with HCºCPh,H. Yan*, B. C. Noll and T. P.  Fehlner*, J. Am.Chem. Soc.2005, 127, 4831-4844.


41.Ruthenacarboranes from the reaction of  nido-1,2-(Cp*RuH)2B3H7 with HCºCC(O)OMe, Cp*=h5-C5Me5. Hydrometallation, alkyne incorporation and functional group modification via cooperative metal-boron interactions within a metallaborane cluster, H. Yan*, A. M. Beatty and T.  P.  Fehlner*, J. Am.Chem. Soc.2003, 125, 16367-16382.


40.Reactionsof nido-1,2-(Cp*RuH)2B3H7 with RCºCR’ (R=H, Me; R’=Ph, Me) to yield novel metallacarboranes,H. Yan,  A. M. Beatty and T. P. Fehlner*, J. Organomet. Chem. 2003, 680, 66-80. 

39. Facile hydrometallation of alkynes by nido-1,2-(Cp*RH)2B3H7 yielding novel Ru-B edge-bridging  carbenes.  Stepwise conversion of HCºCC(O)OMe into nido-1,2-(Cp*RH)2-3-HOB-4-MeC-5-MeOC-BH3, Cp*=h5-C5Me5,H. Yan, A. M. Beatty and T. P. Fehlner*, J. Am. Chem. Soc.2002, 124, 10280-10281.


38. Reaction of 2-butyne with nido-1,2-(Cp*RuH)2B3H7. Improved kinetic control leads to metallacarboranes of novel composition and structure,H. Yan, A. M. Beatty and T. P.Fehlner*, Angew. Chem., Int. Ed. 2002, 41, 2578-2581. (highlighted by C&EN)


37.  Metallaborane reaction chemistry. Nido-dirhodapentaborane isomer structures and stabilies and utilization of dirhodaboranes as homogeneous catalysts for alkyne cyclotrimerization, H. Yan, A. M. Beatty and T. P. Fehlner*, Organometallics, 2002, 21, 5029-5037.


36.  Metal-induced B–H activation. Addition of acetylene, propyne, or 3-methoxypropyne to Rh(Cp*), Ir(Cp*), Ru(p-cymene), and Os(p-cymene) halfsandwich complexes containing a chelating 1,2-dicarba-closo-dodecarborane-1,2-dichalcogenolato ligand, M.Herberhold*, H. Yan, W. Milius and B. Wrackmeyer*, Chem. Eur. J.  2002, 8, 388-395.


35. Reactivity of dimetallapentaboranes, nido-Cp*2M2B3H7, with alkynes. Insertion to form a ruthenacarborane(M=RuH) vs catalytic cyclotrimerization to form arenes(M=Rh), H. Yan, A. M. Beatty and T. P. Fehlner*, Angew. Chem., Int. Ed.2001, 40, 4498-4500.


34.  Metal-induced B–H activation in Cp*Rh, Cp*Ir, (p-cymene)Ru, and (p-cymene)Os half-sandwich  complexes containing the 1,2-dicarba-closo-dodecaborane(12)-1,2-dichalcogenolato ligand, B. Wrackmeyer*, H. Yan, W. Milius and M.Herberhold*, Russ. Chem. Bull.2001, 50, 1518-1524.


33.Selective stepwise carborane substitution in B(3,6)-positions in Cp*Ir halfsandwich complexes containing a chelating 1,2-dicarba-closo-dodecarborane-1,2-dichalcogenolato ligand,  M. Herberhold*, H. Yan, W. Milius and B. Wrackmeyer,  J. C. S. Dalton Trans. 2001, 1782-1789.  


32. The dimerization of ethynylferrocene catalysed by a Cp*Rh 16e halfsandwich complex containing a chelating 1,2-dicarba-closo-dodecarborane-1,2-diselenolate ligand, M. Herberhold*, H. Yan, W.Milius and B. Wrackmeyer*,J. Organomet. Chem.2001, 623, 149-152.


31. Reactivity of Cp*Rh 16e halfsandwich complexes containing a chelating 1,2-dicarba-closo-dodecarborane-1,2-dichalcogenolate ligand. Intermediates in the catalytic trimerization of methyl acetylene monocarboxylate and phenylacetylene, M.Herberhold*, H. Yan, W. Milius andB. Wrackmeyer*Organometallics,2000, 19, 4289-4294.


30.Metal-induced B–H activation. Addition of methyl acetylene carboxylates to Cp*Rh and Cp*Ir  halfsandwich complexes containing the chelating 1,2-dicarba-closo-dodecarborane-1,2- diselenolate  ligand, M. Herberhold*, H. Yan, W. Milius and B. Wrackmeyer*Z. Anorg. Allg. Chem.2000, 626, 1627-1633.


29. Metal-induced B–H activation. Addition of methyl acetylene carboxylates to Cp*Rh-, Cp*Ir-, (p-cymene) Ru- and (p-cymene)Os halfsandwich complexes containing the chelating 1,2-dicarba- closo-dodecarborane-1,2-dithiolate ligand, M. Herberhold*, H. Yan, W. Milius and  B. Wrackmeyer*, Chem. Eur. J.2000, 6, 3026-3032.


28. Metal-induced B–H activation. The addition of phenylacetylene to Cp*Rh-, Cp*Ir-, (p-cymene) Ru-and (p-cymene)Os halfsandwich complexes containing a chelating 1,2-dicarba-closo-dodecarborane-1,2-dichalcogenolate ligand, M. Herberhold*, H. Yan, W. Milius and  B. Wrackmeyer*, J. Organomet. Chem.2000, 604, 170-177.


27. The 16-electron dithiolene complexes (p-cymene)M[S2C2B10H10](M=Ru, Os) containing both h6-(p-cymene) and h2-(ortho-carborane-dithiolate). Adduct formation with Lewis bases, and X-ray crystal structures of {(p-cymene)Ru[S2C2B10H10]}L(L=PPh3) and {(p-cymene)-Ru[S2C2B10H10]}2(m-LL)(LL=PPh2CH2CH2PPh2 and NH2NH2), M. Herberhold*, H. Yan and W. Milius, J. Organomet. Chem.2000, 598, 142-149.


26. Rhodium-induced selective B(3)/B(6)-disubstitution of ortho-carborane-1,2-dithiolate,M. Herberhold*, H. Yan, W. Milius and B. Wrackmeyer*Angew. Chem., Int. Ed.1999, 38, 3689-3691.  (VIP paper)


25. 16e and 18e Cp*Rh halfsandwich complexes containing the 1,2-dicarba-closo-dode-carborane-1,2-dichalcogenolato ligands, as studied by multinuclear NMR, M. Herberhold*, G. X. Jin, H. Yan, W. Milius and B. Wrackmeyer, J. Organomet.Chem.  1999, 587, 252-257.


24. The NMR spectroscopic and X-ray structural characterization of two Cp*Ir halfsandwich complexes containing the 1,2-dicarba-closo-dodecarborane-1,2-diselenolato ligand M. Herberhold*, G. X. Jin,  H. Yan, W. Milius and B. Wrackmeyer, Eur. J. Inorg. Chem.  1999, 1999, 873-875.


23. Synthese, photophysics, and fluxional properties of luminescent A-fram diplatinum(II) acetylide complexes, V. W. W. Yam*, P. K. Y. Yeung, L. P. Chan, W. M. Kwok, D. L. Phillips, K. L. Yu, R. W. K. Wong, H. Yan and Q. J. Meng, Organometallics,1998, 17, 2590-2596.


22. Mono-, di- and tetra-nuclear p-cymene-ruthenium complexes containing oxlato ligands, H. Yan, G. Süss-Fink*, A. Neels and H. Stoeckli-Evans, J. C. S. Dalton Trans.1997,22, 4345-4350.


21. Oxygenation of methane with atmospheric oxygen in aqueous solution promoted by H2O2 and catalyzed by a vanadate ion-pyrazine-2-carboxylic acid system, G. Süss-Fink*, H. Yan, G. V.  Nizova, S. Stanislas and G.  B. Shulpin,Russ.Chem. Bull.1997, 46, 1801-1803.


20. Study of the thermal decomposition, axial-base equilibrium, and Co-C bond dissociation energy of 2’,5’-dideoxyadenosylcobalamin in ethylene glycol , H. L. Chen*, H. Yan, L. B. Luo, X. X. Cui and W. X. Tang,  J. Inorg. Biochem.  1997, 66, 219-225.


19. The coenzyme B12 analogues--ribosylcobalamins: synthesis, characterization and photolysis studies, B. H. Zhu, Z. H. Liu, H. Yan, J. Liu  and H. L. Chen*,  J. Inorg. Biochem.1997, 65, 45-72.


18. Synthesis and crystal structure of organocobalt(III) complexes with secondary alkyls or bulky Schiff base equatorial ligands, H. L. Chen*, D. Y. Han, T. Li, H. Yan and W. X. Tang,Inorg. Chem.1996, 35, 1502-1508.


17. Kinetic study of stereochemical and other factors governing hydrolitic cleavage of a peptide ligand   in binuclear Palladium(II) complexes, X. H. Chen, L. G. Zhu*, H. Yan,  X. Z. You and N. M.  Kostic,  J. C. S. Dalton Trans.  1996,21, 2653-2658.


16. NMR kinetic study on the reaction of cis-[Pd(en)(H2O)2](NO3)2  with Accysme, X. H. Chen, L. G.  Zhu*, H. Yan, N. M. Kostic and X. Z. You, Chinese Science Bulletin, 1996, 41, 390-390.


15. Preparation and characterization of a new coenzyme B12 analogue containing 2’,3’-dideoxyuridine, B. H. Zhu, H. Yan, L. B. Luo, Z. H. Liu and H. L. Chen*, Chinese Chem.Lett.1996, 7, 503-504.


14. Crystal structure of aqua(N,N’-ethylenebis(salicylideniminato))(iso-butyl)Co(III),  H. L. Chen*, D. Y. Han, H. Yan and W. X. Tang, Acta Cryst.1996, C52, 2204-2206.


13. Synthesis and characterization of coenzyme B12 base-off form analogies-2’-deoxy-nucleosidylcobinamide, L. B. Luo, H. L.Chen*, Z. Wu, H. Yan and W. X.Tang, J. Inorg. Biochem.1996, 61, 15-23.


12. Synthesis and spectroscopic properies of  base-off  coenzyme B12 analogues,  L. B. Luo, H. Yan, H. L. Chen* and  W. X. Tang,  Acta Chimica Sinica,1996, 54, 1030-1036.


11. Structural and electronic similarity but functional difference in methylmalonyl-CoA mutase between coenzyme B 12 and the analog 2’,5’-dideoxyadenosylcobalamin,  A. M. Calafat, S.  Taoka, J. M. Puckett, Jr., C. Semerad, H. Yan, L. B. Luo, H. L. Chen*, R. Banerjee* and L. G. Marzilli*, Biochem.1995, 34, 14125-14130.


10. Synthesis and characterization of cobinamides containing 2’-deoxynucleosides---A new kind of  vitamin B12 coenzyme analogues, H. L. Chen*, Z. Wu, L. B. Luo, B. H. Zhu, H. Yan W. X.Tang, Chinese Chem. lett.1994, 5, 377-378.


9. Preparation and spectroscopic properties of 2’,5’-dideoxynucleosidylcobalamins, H. Yan, H. L. Chen*, D. P. Xue, H. Z. Sun and W. X. Tang, Chinese J. Chem. 1994, 12, 33-42.


8. The first study on 2’,5’-dideoxynucleosidyl radicals formed from the anaerobic photolysis of  2’,5’-dideoxynucleosidylcobalamins by ESR spin-trapping technique,  H. Yan, H. L.Chen*, Y. Qian, and W. X. Tang,  J. Inorg. Biochem.1994, 56, 265-271.


7. Synthesis and crystal structure of pyridine[N,N’-ethylenebis(salicylideneiminato)](iso-butyl)  cobalt(III), H. L. Chen*, D. Y. Han, H. Yan, W. X. Tang, Y. Yang and H. Q. Wang, Polyhedron, 1993, 12, 1097-1099.


6. Synthesis and characterization of coenzyme B  12 analogues containing 2’-deoxynucleoside, H. L. Chen*, H. Yan,  H. Z. Sun and W. X. Tang,  Synth. React. Inorg. Metal-Org. Chem.  1993, 23, 347-358.


5. UV-visible spectra and thermodynamic studies of 2’,5’-dideoxynucleosidylcobalamins,  H. L. Chen*, H. Yan and W. X. Tang,  J. Inorg. Biochem.  1993, 52, 109-120.


4. Two dimentional 1H NMR studies on 2’,5’-dideoxyadenosylcobalamin, H. Yan, H. Z. Sun, H. L. Chen* and W. X. Tang, Spectrosc. Lett.  1993, 26, 319-329.


3. Crystal  structure of Co 3(CO)6(m3-S)(:COCH2CH2NH)(m,h2-SCOCH2CH2N) containing a carbene ligand and a bridging bidentate ligand, Q. W. Liu, X. Hu*, S. T. Liu*, H Yan, B. F. Wu, Z. X. Jin and J. Q. Shi,  Polyhedron, 1993, 12, 1527-1532.


2. An improved method to synthesize vitamin B12 coenzyme analogues containing 2’-deoxy-ribonucleoside, H. L.Chen*, H. Yan and W. X. Tang, Chinese Chem. Lett.  1992, 3, 245-246.


1. Studies on cobalt clusters V----Syntheses and structures of sulfur-capped trinuclear cobalt carbonyl clusters containing bridged thiourea moiety, S. T. Liu*, H. Yan, X. Hu* and Q. W. Liu, Acta Chimica Sinica, 1992, 51, 1173-1177.

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