Welcome to the Shi Group
65. Jiahang Lv,§ Xiangyang Chen,§ Xiao-Song Xue, Binlin Zhao, Yong Liang, Minyan Wang, Liqun Jin, Yu Yuan, Ying Han, Yue Zhao,Yi Lu, Jing Zhao, Wei-Yin Sun, Kendall. N. Houk* and Zhuangzhi Shi,* Metal-Free Directed sp2-C–H Borylation, Nature 2019, 575, 336. 
64. Pan Gao, Guoqiang Wang, Longlong Xi, Minyan Wang, Shuhua Li* and Zhuangzhi Shi,* Transition-Metal-Free Defluorosilylation of Fluoroalkenes withSilylboronates, Chin. J. Chem. 2019, 37, 1009.
63. Binlin Zhao, Minyan Wang* and Zhuangzhi Shi,* Single-Electron-Transfer-Induced C(sp3)-N Couplings via C-C BondCleavage of Cycloketoxime Esters, J. Org. Chem. 2019, 84, 10145.
62. Xiaowei Han, Jiefeng Hu, Cheng Chen, Yu Yuan and Zhuangzhi Shi,* Copper-Catalysed, Diboron-Mediated cis-Dideuterated Semihydrogenation of Alkyneswith Heavy Water, Chem. Commun. 2019, 55, 6922.
61. Xiaowei Han, Yu Yuan* and Zhuangzhi Shi,* Rhodium-Catalyzed Selective C-H Trideuteromethylation of Indoleat C7 Position Using Acetic-d6 Anhydride, J. Org. Chem. DOI:10.1021/acs.joc.9b01114.
60. Dingyi Wang,§ Ben Dong,§ Yandong Wang, Jiasheng Qian, Jinjun Zhu, Yue Zhao and Zhuangzhi Shi,* Rhodium-Catalysed Direct Hydroarylation of Alkenesand Alkynes with Phosphines throughPhosphorous-Assisted C-H Activation, Nat. Commun. 2019, 10, 3539.
59. Dingyi Wang, Yunfei Zhao, Chengkai Yuan, Jian Wen, Yue Zhao and Zhuangzhi Shi,* Rhodium(II)-Catalyzed Dehydrogenative Silylation of Biaryl-TypeMonophosphines with Hydrosilanes, Angew. Chem. Int. Ed. 2019, 58, 12529.
58. Binlin Zhao,§ Zexian Li,§ Yixiao Wu, Yandong Wang, Jiasheng Qian, Yu Yuan and Zhuangzhi Shi,* An Olefinic 1,2-Boryl-Migration Enabled by Radical Addition:Construction of gem-Bis(boryl)alkanes, Angew. Chem. Int. Ed. 2019, 58, 9448.
57. Panpan Wang,§ Binlin Zhao,§ Yu Yuan* and Zhuangzhi Shi,* Radical-Induced Ring-Opening and Reconstructionof Cyclobutanone Oxime Esters, Chem. Commun. 2019, 55, 1971.
56. Jian Wen, Dingyi Wang, Jiasheng Qian, Di Wang, Chendan Zhu, Yue Zhao and Zhuangzhi Shi,* Rhodium-Catalyzed PIII-Directed ortho-C-H Borylation ofArylphosphines, Angew. Chem. Int. Ed. 2019, 58, 2078.
55. Xiaodong Qiu,§ Panpan Wang,§ Dingyi Wang, Minyan Wang, Yu Yuan and Zhuangzhi Shi,* PIII-Chelation-Assisted Indole C7-Arylation, Olefination, Methylation,and Acylation with Carboxylic Acids/Anhydrides by RhodiumCatalysis, Angew. Chem. Int. Ed. 2019, 58, 1504.
54. Xiaodong Qiu, Hong Deng, Yue Zhao and Zhuangzhi Shi,* Rhodium-catalyzed, P-directed selective C7 arylation of indoles, Sci. Adv. 2018, 4, aau6468.
53. Jiefeng Hu, Yue Zhao and Zhuangzhi Shi,* Highly Tunable Multi-Borylation of gem-Difluoroalkenes via Copper Catalysis, Nat. Catal. 2018, 1, 860.
52. Di Wang, Xiao-Song Xue, Kendall N. Houk* and Zhuangzhi Shi,* Mild Ring-Opening 1,3-Hydroborations of Non-Activated Cyclopropanes, Angew. Chem. Int. Ed. 2018, 57, 16861.
51. Ting Wang, Liyan Zhou, Youqing Yang, Xinhao Zhang,* Zhuangzhi Shi,* and Yun-Dong Wu,* Directing Effects on the Copper-Catalyzed Site-Selective Arylation of Indoles, Org. Lett. 2018, 20, 6502.
50. Jiefeng Hu, Guoqiang Wang, Shuhua Li* and Zhuangzhi Shi,* Selective C-N Borylation of Alkyl Amines Promoted by Lewis Base, Angew. Chem. Int. Ed. 2018, 57, 15227.
49. Binlin Zhao,§ Cheng Chen,§ Jiahang Lv, Zexian Li, Yu Yuan and Zhuangzhi Shi,* Photoinduced Fragmentation-Rearrangement Sequence of Cycloketoxime Esters, Org. Chem. Front. 2018, 5, 2719.
48. Binlin Zhao, Hui Tan, Cheng Chen, Ning Jiao* and Zhuangzhi Shi,* Photoinduced C-C Bond Cleavage and Oxidation of Cycloketoxime Esters, Chin. J. Chem. 2018, 36, 995.
47. Pan Gao, Chengkai Yuan, Yue Zhao and Zhuangzhi Shi,* Copper-Catalyzed Asymmetric Defluoroborylation of 1-(Trifluoromethyl)Alkenes, Chem. 2018. 4, 2201.
46. Jiahang Lv,§ Binlin Zhao,§ Li Liu, Ying Han,* Yu Yuan* and Zhuangzhi Shi,* Boron Trichloride-Mediated Synthesis of Indoles via the Aminoboration of Alkynes, Adv. Synth. Catal.2018. 360, 4054.
45. Minyan Wang, Xinghui Pu, Yunfei Zhao, Panpan Wang, Zexian Li, Chendan Zhu and Zhuangzhi Shi,* Enantioselective Copper-Catalyzed Defluoroalkylation Using Arylboronate-Activated Alkyl Grignard Reagents, J. Am. Chem. Soc. 2018, 140, 9061.
44. Arun Jyoti Borah and Zhuangzhi Shi,* Rhodium-Catalyzed, Remote Terminal Hydroarylation of Activated Olefins through a Long-Range Deconjugative Isomerization, J. Am. Chem. Soc. 2018, 140, 6062.
43. Chendan Zhu, Di Wang, Dingyi Wang, Yue Zhao, Wei-Yin Sun and Zhuangzhi Shi,* Bottom-up Construction of π-Extended Arenes by a Palladium-Catalyzed Annulative Dimerization of o-Iodobiaryl Compounds, Angew. Chem. Int. Ed. 2018, 57, 8848.
# Frontispiece artical.
42. Youqing Yang and Zhuangzhi Shi,* Regioselective Direct Arylation of Indoles on the Benzenoid Moiety, Chem. Commun. 2018, 54, 1676.
# Feature artical
41. Chendan Zhu, Dingyi Wang, Yue Zhao, Wei-Yin Sun, and Zhuangzhi Shi,* Enantioselective Palladium-Catalyzed Intramolecular α-Arylative Desymmetrization of 1,3-Diketones, J. Am. Chem. Soc. 2017, 139, 16486.
40. Jiefeng Hu,§ Xiaowei Han,§ Yu Yuan, and Zhuangzhi Shi,* Stereoselective Synthesis of Z-Fluoroalkenes by Copper-Catalyzed Hydrodefluorination of gem-Difluoroalkenes with Water, Angew. Chem. Int. Ed. 2017, 56, 13342.
39.Binlin Zhao, Zhuangzhi Shi,* Copper-Catalyzed Intermolecular Heck-Like Coupling of Cyclobutanone Oximes Initiated by Selective C-C Bond Cleavage, Angew. Chem. Int. Ed. 2017, 56, 12727.
38. Xiaodong Qiu,§ Minyan Wang,§ Yue Zhao, Zhuangzhi Shi,* Rhodium(I)-Catalyzed Tertiary Phosphine Directed C-H Arylation: Rapid Construction of Ligand Libraries, Angew. Chem. Int. Ed. 2017, 56, 7233.
37. Arun Jyoti Boraha, and Zhuangzhi Shi,* Palladium-Catalyzed Regioselective C-H Fluoroalkylation of Indoles at C4-Position, Chem. Commun. 2017, 53, 3945.
36. Youqing Yang,§ Pan Gao,§ Yue Zhao, and Zhuangzhi Shi,* Regiocontrolled Direct C-H Arylation of Indoles at the C4 and C5 Positions, Angew. Chem. Int. Ed. 2017, 56, 3966. (§Both authors contributed equally)
35. Jiefeng Hu, Minyan Wang, Xinghui Pu, and Zhuangzhi Shi,* Nickel-Catalyzed Retro-Hydroamidocarbonylation of Aliphatic Amides to Olefins, Nat. Commun. 2017, 8, 14993.
34. Xinghui Pu, Jiefeng Hu, Yue Zhao, and Zhuangzhi Shi,* Nickel-Catalyzed Decarbonylative Borylation and Silylation of Esters, ACS Catal. 2016, 6, 6692.
33. ChendanZhu, Yue Zhao, Di Wang, Wei-Yin Sun and Zhuangzhi Shi,* Palladium-Catalyzed Direct Arylation andCyclization of o-Iodobiaryls to A Library of Tetraphenylenes, Sci. Rep. 2016, 6, 33131.
32. Youqing Yang, Ruirui Li, Yue Zhao, Dongbing Zhao, and Zhuangzhi Shi,* Cu-Catalyzed Direct C6-Arylation of Indoles, J. Am. Chem. Soc. 2016, 138, 8734.
31. Pan Gao, Zhuangzhi Shi,* and Yu Yuan,* Iridium(III)-Catalyzed Regioselective Direct Arylation of sp2 C-H Bonds with Diaryliodonium Salts, Org. Biomol. Chem. 2016, 14, 7109.
30. Jiefeng Hu, Yue Zhao, Jingjing Liu, Yemin Zhang, and Zhuangzhi Shi,* Nickel-Catalyzed Decarbonylative Borylation of Amides: Evidence for Acyl C-N Bond Activation, Angew. Chem. Int. Ed. 2016, 55, 8718.
29. Binlin Zhao, Zhuangzhi Shi,* and Yu Yuan,* Transition-metal-catalyzed Chelation-assisted C–H Functionalization of Aromatic Substrates, Chem. Rec. 2016, 16, 886.
28. Yucheng Mu, Xiaodong Tan, Yemin Zhang, Xiaobi Jing, and Zhuangzhi Shi,* Pd(II)-catalyzed β-C–H arylation of O-methyl ketoximes with iodoarenes, Org. Chem. Front. 2016, 3, 380.
# 2015 Emerging Investigators by OCF.
27. Youqing Yang, Xiaodong Qiu, Yue Zhao, Yucheng Mu, and Zhuangzhi Shi,* Palladium-Catalyzed C–H Arylation of Indoles at the C7-Position, J. Am. Chem. Soc. 2016, 138, 495.
# Top 2 most read articles from the 1 month list.
26. Jiefeng Hu, Heqing Sun, Wangshui Cai, Xinghui Pu, Yemin Zhang, and Zhuangzhi Shi,* Nickel-Catalyzed Borylation of Aryl- and Benzyltrimethylammonium Salts via C-N Bond Cleavage, J. Org. Chem. 2016, 81, 14.
# JOC Featured Articles.
25. Invited Highlights: Yucheng Mu, Chendan Zhu, and Zhuangzhi Shi,* Memory of Chirality (MOC) in Intramolecular sp3 C-H Amination, Synlett 2016, 27,486.
24. Pan Gao, Wei Guo, Jingjing Xue, Yue Zhao, Yu Yuan, Yuanzhi Xia,* and Zhuangzhi Shi,* Iridium(III)-Catalyzed Direct Arylation of C-H Bonds with Diaryliodonium Salts, J. Am. Chem. Soc. 2015, 137, 12231.
# Top 5 most read articles from the 1 month list.
23. Chendan Zhu, Yong Liang, Xin Hong, Heqing Sun, Wei-Yin Sun, K. N. Houk,* and Zhuangzhi Shi,* Iodoarene-Catalyzed Stereospecific Intramolecular sp3 C-H Amination: Reaction Development and Mechanistic Insights, J. Am. Chem. Soc. 2015, 137, 7564.
# Top 20 most read articles from the 1 month list.
# Highlighted by Synlett 2016, 27,486.
2011-2014 Postdoc Resarch
22. Z. Shi, M. Boultadakis-Arapinis, D. C. Koester, F. Glorius,* Rh(III)-Catalyzed Intramolecular Redox-Neutral Cyclization of Alkenes via C-H Activation, Chem. Comm. 2014, 50, 650-2652.
21. D. Zhao,§ Z. Shi,§ F. Glorius,* Rh(III)-Catalyzed Hydrazine-Directed Redox-Neutral C-H Activation via the Cleavage of an N-N Bond: An General Access to Diverse Indoles, Angew. Chem. Int. Ed. 2013, 52, 12426-12429. (§ Both authors contributed equally)
20. Z. Shi, D. C. Koester, M. Boultadakis-Arapinis, F. Glorius,* Rh(III)-Catalyzed Synthesis of Multisubstituted Isoquinoline and Pyridine N-Oxides from Oximes and Diazo Compounds, J. Am. Chem. Soc. 2013, 135, 12204–12207.
19. Z. Shi, M. Boultadakis-Arapinis, F. Glorius,* Rh(III)-Catalyzed Dehyrogenative Alkylation of (Hetero)Arenes with Allylic Alcohols, Allowing an Aldol Condensation to Indenes, Chem. Comm. 2013, 49, 6489-6491.
18. Z. Shi, C. Grohmann, F. Glorius,* Mild Rh(III)-Catalyzed Cyclization of Amides with α,β-Unsaturated Aldehydes and Ketones to Azepinones: Application to the Synthesis of the Homoprotoberberine Framework, Angew. Chem. Int. Ed. 2013, 52, 5393-5397. Synfacts, 2013, 9, 0828.
17. Z. Shi,§ M. Suri,§ F. Glorius,* Aerobic Synthesis of Pyrroles and Dihydropyrroles from Imines: Pd(II)-Catalyzed Intramolecular C-H Dehydrogenative Cyclization, Angew. Chem. Int. Ed. 2013, 52, 4892-4896. (§ Both authors contributed equally)
16. Z. Shi, F. Glorius,* Synthesis of Fluorenones via Quaternary Ammonium Salt-Promoted Intramolecular Dehydrogenative Arylation of Aldehydes, Chem. Sci. 2013, 4, 829-833. Synform, 2013, 13, A71.
15. Z. Shi, F. Glorius,* Efficient and Versatile Indole Synthesis from Enamines and Imines via Cross-Dehydrogenative Coupling, Angew. Chem. Int. Ed. 2012, 51, 9220-9222.
14. Z. Shi, N. Schroder, F. Glorius,* Rh[III]-Catalyzed Dehydrogenative Heck Reaction (DHR) of Salicylaldehydes, Angew. Chem. Int. Ed. 2012, 51, 8092-8096; Synfacts, 2012, 8, 1211.
2008-2011 Ph.D. Resarch
13. L. Ren, Z. Shi, N. Jiao,* Pd(II)-Catalyzed Aerobic Oxidative Intramolecular Hydroamination and C-H Functionalization of N-Alkynyl Anilines for the Synthesis of Indole Derivatives, Tetrahedron 2013, 69, 4408-4414.
12. Z. Shi, C. Zhang, C. Tang, N. Jiao,* Recent Advances in Transition-metal Catalyzed Reactions Using Molecular Oxygen as the Oxidant, Chem. Soc. Rev. 2012, 41, 3381-3430.
11. Z. Shi,§ C. Tang,§ N. Jiao,* Chemoselective Synthesis of Naphthylamides and Isoquinolinones via Rhodium-Catalyzed Oxidative Dehydrogenative Annulation of Benzamides with Alkynes, Adv. Syn. Cat. 2012, 354, 2695-2700. (§ Both authors contributed equally)
10. R. Lin, S. Ding, Z. Shi, N. Jiao,* An Efficient Difluorohydroxylation of Indoles Using Selectfluor as a Fluorinating Reagent, Org. Lett. 2011, 13, 4498-4501.
9. Z. Shi, B. Zhang, Y. Cui, N. Jiao,* Palladium-Catalyzed Ring-expansion Reaction of Indoles with Alkynes: From Indoles to Tetrahydroquinoline Derivatives Under Mild Conditions, Angew. Chem. Int. Ed. 2010, 49, 4036-4041.
8. S. Ding, Z. Shi, N. Jiao,* Pd(II)-Catalyzed Synthesis of Carbolines by Iminoannulation of Internal Alkynes via Direct C?H Bond Cleavage Using Dioxygen as Oxidant, Org. Lett. 2010, 12, 1540-1543.
7. Z. Shi, Y. Cui, N. Jiao,* Synthesis of β- and γ-Carbolinones via Pd-Catalyzed Direct Dehydrogenative Annulation (DDA) of Indole-carboxamides with Alkynes Using Air as the Oxidant, Org. Lett. 2010, 12, 2908-2911.
6. Z. Shi, S. Ding, Y. Cui, N. Jiao,* A Palladium-Catalyzed Oxidative Cycloaromatization of Biaryls with Alkynes Using Molecular Oxygen as the Oxidant, Angew. Chem. Int. Ed. 2009, 48, 7895-7898.
5. Z. Shi, C. Zhang, S. Li, D. Pan, S. Ding, Y. Cui, N. Jiao,* Indoles from Simple Anilines and Alkynes: Palladium-Catalyzed C-H Activation Using Dioxygen as the Oxidant, Angew. Chem. Int. Ed. 2009, 48, 4572-4576, “Hot Paper”; Synfacts, 2009, 8, 846-846; “Nature China”highlight.
2005-2008 M.S. Resarch
4. F. Zhang, Z. Shi, F. Chen, Y. Yuan,* An Efficient MnCl2-catalyzed Tandem Acylation-Cross-coupling Reaction of o-Halobenzoyl Chloride with Diorganyl Magnesium Compound, Appl. Organometal. Chem. 2010, 24, 57-63.
3. Y. Yuan,* Z. Shi, Indium(III)-Catalyzed Addition of 1,3-Dicarbonyl Compounds to Alkenes, Synlett 2007, 3219-3223.
2. Y. Yuan,* Z. Shi, X. Feng, X. Liu, Solvent-free Reactions of Alcohols with β-Dicarbonyl Compounds Catalyzed by Iron(III) Chloride, Appl. Organometal. Chem .2007, 21, 958-964.
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2. 史壮志、赵云霏、王敏燕；一种二芳基并噻吩型或二芳基硫醚型氘代烷基制备方法；专利（申请）号：201810770921.4
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