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Publications
2019

65. Jiahang Lv,§ Xiangyang Chen,§ Xiao-Song Xue, Binlin Zhao, Yong Liang, Minyan Wang, Liqun Jin, Yu Yuan, Ying Han, Yue Zhao,Yi Lu, Jing Zhao, Wei-Yin Sun, Kendall. N. Houk* and Zhuangzhi Shi,* Metal-Free Directed sp2-C–H Borylation, Nature 2019, 575, 336. 

64. Pan Gao, Guoqiang Wang, Longlong Xi, Minyan Wang, Shuhua Li* and Zhuangzhi Shi,* Transition-Metal-Free Defluorosilylation of Fluoroalkenes withSilylboronates, Chin. J. Chem. 201937, 1009. 


63. Binlin Zhao, Minyan Wang* and Zhuangzhi Shi,* Single-Electron-Transfer-Induced C(sp3)-N Couplings via C-C BondCleavage of Cycloketoxime Esters, J. Org. Chem. 2019, 84, 10145. 


62. Xiaowei Han, Jiefeng Hu, Cheng Chen, Yu Yuan and Zhuangzhi Shi,* Copper-Catalysed, Diboron-Mediated cis-Dideuterated Semihydrogenation of Alkyneswith Heavy Water, Chem. Commun. 2019, 55, 6922. 


61. Xiaowei Han, Yu Yuan* and Zhuangzhi Shi,* Rhodium-Catalyzed Selective C-H Trideuteromethylation of Indoleat C7 Position Using Acetic-d6 Anhydride, J. Org. Chem. DOI:10.1021/acs.joc.9b01114


60. Dingyi Wang,§ Ben Dong,§ Yandong Wang, Jiasheng Qian, Jinjun Zhu, Yue Zhao and Zhuangzhi Shi,* Rhodium-Catalysed Direct Hydroarylation of Alkenesand Alkynes with Phosphines throughPhosphorous-Assisted C-H Activation, Nat. Commun. 2019, 10, 3539. 


59. Dingyi Wang, Yunfei Zhao, Chengkai Yuan, Jian Wen, Yue Zhao and Zhuangzhi Shi,* Rhodium(II)-Catalyzed Dehydrogenative Silylation of Biaryl-TypeMonophosphines with Hydrosilanes, Angew. Chem. Int. Ed. 2019, 58, 12529


58. Binlin Zhao,§ Zexian Li,§ Yixiao Wu, Yandong Wang, Jiasheng Qian, Yu Yuan and Zhuangzhi Shi,* An Olefinic 1,2-Boryl-Migration Enabled by Radical Addition:Construction of gem-Bis(boryl)alkanes, Angew. Chem. Int. Ed. 2019, 58, 9448


57. Panpan Wang,§ Binlin Zhao,§ Yu Yuan* and Zhuangzhi Shi,* Radical-Induced Ring-Opening and Reconstructionof Cyclobutanone Oxime Esters, Chem. Commun. 201955, 1971. 


56. Jian Wen, Dingyi Wang, Jiasheng Qian, Di Wang, Chendan Zhu, Yue Zhao and Zhuangzhi Shi,* Rhodium-Catalyzed PIII-Directed ortho-C-H Borylation ofArylphosphines, Angew. Chem. Int. Ed. 201958, 2078. 


55. Xiaodong Qiu,§ Panpan Wang,§ Dingyi Wang, Minyan Wang, Yu Yuan and Zhuangzhi Shi,* PIII-Chelation-Assisted Indole C7-Arylation, Olefination, Methylation,and Acylation with Carboxylic Acids/Anhydrides by RhodiumCatalysis, Angew. Chem. Int. Ed. 2019, 58, 1504. 

2018

54. Xiaodong Qiu, Hong Deng, Yue Zhao and Zhuangzhi Shi,* Rhodium-catalyzed, P-directed selective C7 arylation of indoles, Sci. Adv. 2018, 4, aau6468.  


53. Jiefeng Hu, Yue Zhao and Zhuangzhi Shi,* Highly Tunable Multi-Borylation of gem-Difluoroalkenes via Copper Catalysis, Nat. Catal. 20181, 860. 



52. Di Wang, Xiao-Song Xue, Kendall N. Houk* and Zhuangzhi Shi,* Mild Ring-Opening 1,3-Hydroborations of Non-Activated Cyclopropanes, Angew. Chem. Int. Ed. 201857, 16861.


51. Ting Wang, Liyan Zhou, Youqing Yang, Xinhao Zhang,* Zhuangzhi Shi,* and Yun-Dong Wu,* Directing Effects on the Copper-Catalyzed Site-Selective Arylation of  Indoles, Org. Lett. 2018, 20, 6502. 



50. Jiefeng Hu, Guoqiang Wang, Shuhua Li* and Zhuangzhi Shi,* Selective C-N Borylation of Alkyl Amines Promoted by Lewis Base, Angew. Chem. Int. Ed. 2018, 57, 15227. 


49. Binlin Zhao,§ Cheng Chen,§ Jiahang Lv, Zexian Li, Yu Yuan and Zhuangzhi Shi,* Photoinduced Fragmentation-Rearrangement Sequence of Cycloketoxime Esters, Org. Chem. Front. 2018, 5, 2719. 


48. Binlin Zhao, Hui Tan, Cheng Chen, Ning Jiao* and Zhuangzhi Shi,* Photoinduced C-C Bond Cleavage and Oxidation of Cycloketoxime Esters, Chin. J. Chem. 2018, 36, 995. 




47. Pan Gao, Chengkai Yuan, Yue Zhao and Zhuangzhi Shi,* Copper-Catalyzed Asymmetric Defluoroborylation of 1-(Trifluoromethyl)Alkenes, Chem. 2018. 4, 2201. 



46. Jiahang Lv,§ Binlin Zhao,§ Li Liu, Ying Han,* Yu Yuan* and Zhuangzhi Shi,* Boron Trichloride-Mediated Synthesis of Indoles via the Aminoboration of Alkynes, Adv. Synth. Catal.2018. 360, 4054. 



45. Minyan Wang, Xinghui Pu, Yunfei Zhao, Panpan Wang, Zexian Li, Chendan Zhu and Zhuangzhi Shi,* Enantioselective Copper-Catalyzed Defluoroalkylation Using Arylboronate-Activated Alkyl Grignard Reagents, J. Am. Chem. Soc. 2018, 140, 9061. 


44. Arun Jyoti Borah and Zhuangzhi Shi,* Rhodium-Catalyzed, Remote Terminal Hydroarylation of Activated Olefins through a Long-Range Deconjugative Isomerization, J. Am. Chem. Soc. 2018140, 6062. 




43. Chendan Zhu, Di Wang, Dingyi Wang, Yue Zhao, Wei-Yin Sun and Zhuangzhi Shi,* Bottom-up Construction of π-Extended Arenes by a Palladium-Catalyzed Annulative Dimerization of o-Iodobiaryl Compounds,  Angew. Chem. Int. Ed. 201857, 8848. 

# Frontispiece artical.



42. Youqing Yang  and  Zhuangzhi Shi,* Regioselective Direct Arylation of Indoles on the Benzenoid Moiety,  Chem. Commun. 2018, 54, 1676. 

# Feature artical



2017

41. Chendan Zhu, Dingyi Wang, Yue Zhao, Wei-Yin Sun, and Zhuangzhi Shi,* Enantioselective Palladium-Catalyzed Intramolecular α-Arylative Desymmetrization of 1,3-Diketones,  J. Am. Chem. Soc. 2017, 139, 16486. 


40. Jiefeng Hu,§ Xiaowei Han,§ Yu Yuan, and Zhuangzhi Shi,* Stereoselective Synthesis of Z-Fluoroalkenes by Copper-Catalyzed Hydrodefluorination of gem-Difluoroalkenes with Water,  Angew. Chem. Int. Ed. 2017, 56, 13342. 


39.Binlin Zhao, Zhuangzhi Shi,* Copper-Catalyzed Intermolecular Heck-Like Coupling of Cyclobutanone Oximes Initiated by Selective C-C Bond Cleavage, Angew. Chem. Int. Ed. 2017, 56, 12727.  



38. Xiaodong Qiu,§ Minyan Wang,§ Yue Zhao, Zhuangzhi Shi,* Rhodium(I)-Catalyzed Tertiary Phosphine Directed C-H Arylation: Rapid Construction of Ligand Libraries, Angew. Chem. Int. Ed. 2017, 56, 7233. 



37. Arun Jyoti Boraha, and Zhuangzhi Shi,* Palladium-Catalyzed Regioselective C-H Fluoroalkylation of Indoles at C4-Position, Chem. Commun. 2017, 53, 3945.


36. Youqing Yang,§ Pan Gao,§ Yue Zhao, and Zhuangzhi Shi,* Regiocontrolled Direct C-H Arylation of Indoles at the C4 and C5 Positions, Angew. Chem. Int. Ed. 2017, 56, 3966. (§Both authors contributed equally)



35. Jiefeng Hu, Minyan Wang, Xinghui Pu, and Zhuangzhi Shi,* Nickel-Catalyzed Retro-Hydroamidocarbonylation of Aliphatic Amides to Olefins, Nat. Commun. 2017, 8, 14993.  

2016

34. Xinghui Pu, Jiefeng Hu, Yue Zhao, and Zhuangzhi Shi,* Nickel-Catalyzed Decarbonylative Borylation and Silylation of EstersACS Catal. 2016, 6, 6692.  



33. ChendanZhu, Yue Zhao, Di Wang, Wei-Yin Sun and Zhuangzhi Shi,* Palladium-Catalyzed Direct Arylation andCyclization of o-Iodobiaryls to A Library of Tetraphenylenes, Sci. Rep. 2016, 6, 33131.  


32. Youqing Yang, Ruirui Li, Yue Zhao, Dongbing Zhao, and Zhuangzhi Shi,* Cu-Catalyzed Direct C6-Arylation of Indoles, J. Am. Chem. Soc. 2016, 138, 8734.  



31. Pan Gao, Zhuangzhi Shi,* and Yu Yuan,* Iridium(III)-Catalyzed Regioselective Direct Arylation of sp2 C-H Bonds with Diaryliodonium Salts, Org. Biomol. Chem. 2016, 14, 7109. 


30. Jiefeng Hu, Yue Zhao, Jingjing Liu, Yemin Zhang, and Zhuangzhi Shi,* Nickel-Catalyzed Decarbonylative Borylation of Amides: Evidence for Acyl C-N Bond Activation, Angew. Chem. Int. Ed. 201655, 8718. 



29. Binlin Zhao, Zhuangzhi Shi,* and Yu Yuan,* Transition-metal-catalyzed Chelation-assisted C–H Functionalization of Aromatic SubstratesChem. Rec. 2016, 16, 886.  


28. Yucheng Mu, Xiaodong Tan, Yemin Zhang, Xiaobi Jing, and Zhuangzhi Shi,* Pd(II)-catalyzed β-C–H arylation of O-methyl ketoximes with iodoarenesOrg. Chem. Front. 2016, 3, 380.  

# 2015 Emerging Investigators by OCF.


27. Youqing Yang, Xiaodong Qiu, Yue Zhao, Yucheng Mu, and Zhuangzhi Shi,* Palladium-Catalyzed C–H Arylation of Indoles at the C7-PositionJ. Am. Chem. Soc. 2016138, 495.   

# Top 2 most read articles from the 1 month list.


26. Jiefeng Hu, Heqing Sun, Wangshui Cai, Xinghui Pu, Yemin Zhang, and Zhuangzhi Shi,* Nickel-Catalyzed Borylation of Aryl- and Benzyltrimethylammonium Salts via C-N Bond Cleavage, J. Org. Chem. 201681, 14.   


# JOC Featured Articles.


25. Invited Highlights: Yucheng Mu, Chendan Zhu, and Zhuangzhi Shi,* Memory of Chirality (MOC) in Intramolecular sp3 C-H Amination, Synlett 201627,486.   



2015

24. Pan Gao, Wei Guo, Jingjing Xue, Yue Zhao, Yu Yuan, Yuanzhi Xia,* and Zhuangzhi Shi,* Iridium(III)-Catalyzed Direct Arylation of C-H Bonds with Diaryliodonium Salts, J. Am. Chem. Soc. 2015, 137, 12231 

# Top 5 most read articles from the 1 month list.


23. Chendan Zhu, Yong Liang, Xin Hong, Heqing Sun, Wei-Yin Sun, K. N. Houk,* and Zhuangzhi Shi,* Iodoarene-Catalyzed Stereospecific Intramolecular sp3 C-H Amination: Reaction Development and Mechanistic InsightsJ. Am. Chem. Soc. 2015137, 7564 

# Top 20 most read articles from the 1 month list.

Highlighted by Synlett 2016, 27,486.

Before 2014

2011-2014 Postdoc Resarch


22. Z. Shi, M. Boultadakis-Arapinis, D. C. Koester, F. Glorius,* Rh(III)-Catalyzed Intramolecular Redox-Neutral Cyclization of Alkenes via C-H Activation, Chem. Comm. 2014, 50, 650-2652.  


21. D. Zhao,§ Z. Shi,§  F. Glorius,* Rh(III)-Catalyzed Hydrazine-Directed Redox-Neutral C-H Activation via the Cleavage of an N-N Bond: An General Access to Diverse Indoles, Angew. Chem. Int. Ed. 2013, 52, 12426-12429. (§ Both authors contributed equally)


20. Z. Shi, D. C. Koester, M. Boultadakis-Arapinis, F. Glorius,* Rh(III)-Catalyzed Synthesis of Multisubstituted Isoquinoline and Pyridine N-Oxides from Oximes and Diazo Compounds, J. Am. Chem. Soc. 2013, 135, 12204–12207.


19. Z. Shi, M. Boultadakis-Arapinis, F. Glorius,* Rh(III)-Catalyzed Dehyrogenative Alkylation of (Hetero)Arenes with Allylic Alcohols, Allowing an Aldol Condensation to Indenes, Chem. Comm. 2013, 49, 6489-6491.  


18. Z. Shi, C. Grohmann, F. Glorius,* Mild Rh(III)-Catalyzed Cyclization of Amides with α,β-Unsaturated Aldehydes and Ketones to Azepinones:  Application to the Synthesis of the Homoprotoberberine Framework, Angew. Chem. Int. Ed. 2013, 52, 5393-5397. Synfacts, 2013, 9, 0828.


17. Z. Shi,§ M. Suri,§ F. Glorius,* Aerobic Synthesis of Pyrroles and Dihydropyrroles from Imines: Pd(II)-Catalyzed Intramolecular C-H Dehydrogenative Cyclization, Angew. Chem. Int. Ed. 2013, 52, 4892-4896. (§ Both authors contributed equally)


16. Z. Shi, F. Glorius,* Synthesis of Fluorenones via Quaternary Ammonium Salt-Promoted Intramolecular Dehydrogenative Arylation of Aldehydes, Chem. Sci. 2013, 4, 829-833. Synform, 2013, 13, A71.


15. Z. Shi, F. Glorius,* Efficient and Versatile Indole Synthesis from Enamines and Imines via Cross-Dehydrogenative Coupling, Angew. Chem. Int. Ed. 2012, 51, 9220-9222.


14. Z. Shi, N. Schroder, F. Glorius,* Rh[III]-Catalyzed Dehydrogenative Heck Reaction (DHR) of Salicylaldehydes, Angew. Chem. Int. Ed. 2012, 51, 8092-8096; Synfacts, 2012, 8, 1211.


2008-2011 Ph.D. Resarch


13. L. Ren, Z. Shi, N. Jiao,* Pd(II)-Catalyzed Aerobic Oxidative Intramolecular Hydroamination and C-H Functionalization of N-Alkynyl Anilines for the Synthesis of Indole Derivatives, Tetrahedron 2013, 69, 4408-4414.


12. Z. Shi, C. Zhang, C. Tang, N. Jiao,* Recent Advances in Transition-metal Catalyzed Reactions Using Molecular Oxygen as the Oxidant, Chem. Soc. Rev. 2012, 41, 3381-3430.


11. Z. Shi,§ C. Tang,§ N. Jiao,* Chemoselective Synthesis of Naphthylamides and Isoquinolinones via Rhodium-Catalyzed Oxidative Dehydrogenative Annulation of Benzamides with Alkynes, Adv. Syn. Cat. 2012, 354, 2695-2700. (§ Both authors contributed equally)


10. R. Lin, S. Ding, Z. Shi, N. Jiao,* An Efficient Difluorohydroxylation of Indoles Using Selectfluor as a Fluorinating Reagent, Org. Lett. 2011, 13, 4498-4501.


9. Z. Shi, B. Zhang, Y. Cui, N. Jiao,* Palladium-Catalyzed Ring-expansion Reaction of Indoles with Alkynes: From Indoles to Tetrahydroquinoline Derivatives Under Mild Conditions, Angew. Chem. Int. Ed. 2010, 49, 4036-4041.


8. S. Ding, Z. Shi, N. Jiao,* Pd(II)-Catalyzed Synthesis of Carbolines by Iminoannulation of Internal Alkynes via Direct C?H Bond Cleavage Using Dioxygen as Oxidant, Org. Lett. 2010, 12, 1540-1543.


7. Z. Shi, Y. Cui, N. Jiao,* Synthesis of β- and γ-Carbolinones via Pd-Catalyzed Direct Dehydrogenative Annulation (DDA) of Indole-carboxamides with Alkynes Using Air as the Oxidant, Org. Lett. 2010, 12, 2908-2911.


6. Z. Shi, S. Ding, Y. Cui, N. Jiao,* A Palladium-Catalyzed Oxidative Cycloaromatization of Biaryls with Alkynes Using Molecular Oxygen as the Oxidant, Angew. Chem. Int. Ed. 2009, 48, 7895-7898.


5. Z. Shi, C. Zhang, S. Li, D. Pan, S. Ding, Y. Cui, N. Jiao,* Indoles from Simple Anilines and Alkynes: Palladium-Catalyzed C-H Activation Using Dioxygen as the Oxidant, Angew. Chem. Int. Ed. 2009, 48, 4572-4576, “Hot Paper”; Synfacts, 2009, 8, 846-846; “Nature China”highlight.


2005-2008 M.S. Resarch


4. F. Zhang, Z. Shi, F. Chen, Y. Yuan,* An Efficient MnCl2-catalyzed Tandem Acylation-Cross-coupling Reaction of o-Halobenzoyl Chloride with Diorganyl Magnesium Compound, Appl. Organometal. Chem. 2010, 24, 57-63.


3. Y. Yuan,* Z. Shi, Indium(III)-Catalyzed Addition of 1,3-Dicarbonyl Compounds to Alkenes, Synlett 2007, 3219-3223.


2. Y. Yuan,* Z. Shi, X. Feng, X. Liu, Solvent-free Reactions of Alcohols with β-Dicarbonyl Compounds Catalyzed by Iron(III) Chloride, Appl. Organometal. Chem .2007, 21, 958-964.


1. 陈伟锋,史壮志,袁宇,颜朝国不对称自催化反应,化学进展, 200719,456。


3. 史壮志、陈成、赵斌林;一种氘代二甲羟胺苯甲酸酯类化合物及其制备方法和应用;专利(申请)号:201811124878.0


2. 史壮志、赵云霏、王敏燕;一种二芳基并噻吩型或二芳基硫醚型氘代烷基制备方法;专利(申请)号:201810770921.4 


1. 史壮志、邱晓东、王敏燕、赵越、浦兴晖、胡杰峰;芳基取代联苯、吡咯、吲哚或联苯型单膦配体制备方法;专利(申请)号:201611201244.1