State Key laboratory of Coordination Chemistry

School of Chemistry and Chemical Engineering
Nanjing University

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  1. Xing-Cai Huang,*  Zi-Yi Qi, Chen-Long Ji, Yi-Ming  Guo, Shi-Chang Yan,Yi-Quan Zhang,* Dong Shao and Xin-Yi Wang*, High-Coordinate CoII and FeII  compounds Constructed from an Asymmetric Tetradentetra Ligand Showing Slow Magnetic Relaxation Behavior, Dalton Trans. 2018,   DOI: 10.1039/c8dt01829d

  2.       Xiao-Qin  Wei, Qian Pi, Fu-Xing Shen, Dong Shao, Hai-Yan Wei* and Xin-Yi Wang*,Syntheses,  structures, and magnetic properties of three new MnII–[MoIII(CN)7]4−  molecular magnets,Dalton Trans., 2018, DOI:  10.1039/c8dt01433g

  3. Zhao-Xin  Xiao, Hao Miao, Dong Shao, Hai-Yan Wei,* Yi-Quan Zhang* and Xin-Yi Wang*,A  family of lanthanide compounds with reduced nitronyl nitroxide diradical:  syntheses, structures and magnetic properties,Dalton Trans.,2018, 47, 7925.

  4. Dong  Shao, Le Shi, Hai-Yan Wei*, and Xin-Yi  Wang*,Field-induced  single-ion magnet behavior in two cobalt(II) coordination polymers with  2,4,6-tris(4-pyridyl)-1,3,5-triazine, Inorganics, 2017, 5 90.

  5.  Dong-Qing Wu, Dong Shao, Xiao-Qin Wei,      Fu-Xing Shen, Le Shi, Yi-Quan Zhang* and      Xin-Yi Wang*,  Single-ion magnetism in seven-coordinate YbIII      complexes with distorted D5h coordination      geometry, Dalton Trans. 2017,46,9088.

  6.  Dong Shao, Le Shi, Fu-Xing Shen and Xin-Yi Wang*,   A cyano-bridged coordination nanotube showing      field-induced slow magnetic relaxation, CrystEngComm 2017, 19, 5707.

  7.  Dong-Qing Wu,† Dong Shao,† Xiao-Qin Wei,† Fu-Xing Shen,† Le Shi,† David Kempe,‡      Yuan-Zhu Zhang,*,§ Kim R. Dunbar,*,‡ and Xin-Yi Wang*,   Reversible On−Off Switching of a Single-Molecule Magnet via a
          Crystal-to-Crystal Chemical Transformation, J. Am. Chem. Soc. 2017, 139, 11714.

  8. Dong Shao,[a] Lin-Dan Deng,[a] Le Shi,[a] Dong-Qing Wu,[a] Xiao-Qin Wei,[a] Si-Run Yang,[a]      and Xin-Yi Wang*,Slow Magnetic Relaxation and Spin-Crossover Behavior in a Bicomponent Ion-Pair Cobalt(II) Complex, Eur. J. Inorg. Chem. 2017, 3862.

  9.  Xin-Hua Zhao, Lin-Dan Deng, Yan Zhou, Dong Shao, Dong-Qing Wu, Xiao-Qin Wei,and Xin-Yi Wang*,  Slow Magnetic Relaxation in One-Dimensional Azido-Bridged CoII      Complexes, Inorg. Chem. 2017, 56, 8058.

  10. Dong-Qing Wu,† David Kempe,‡ Yan Zhou,† Lin-Dan Deng,† Dong Shao,† Xiao-Qin Wei,† Le Shi,†      Kim R. Dunbar,*,‡ and Xin-Yi Wang*,   Three-Dimensional FeII−[MoIII(CN)7]4− Magnets with Ordering below      65 K and Distinct Topologies Induced by Cation Identity, Inorg. Chem. 2017, 56, 7182.

  11. Jian Wang,a Hao Miao,a Zhao-Xin Xiao,a Yan Zhou,a Lin-Dan Deng,a      Yi-Quan Zhang*b and Xin-Yi Wang *a,  Syntheses, structures and magnetic properties      of the lanthanide complexes of the pyrimidylsubstituted nitronyl nitroxide radical, Dalton Trans. 2017, 46, 10452.

  12.  Dong Shao, Yan Zhou, Qian Pi, Fu-Xing Shen, Si-Run Yang, Shao-Liang Zhang      and Xin-Yi Wang*,   Two-dimensional frameworks formed by      pentagonal bipyramidal cobalt(II) ions and      hexacyanometallates: antiferromagnetic ordering,
          metamagnetism and slow magnetic relaxation, Dalton Trans, 2017, 46, 9088.

  13. Xing-Cai Huang, Xin-Hua Zhao,Dong Shaoa and Xin-Yi Wang*,  Syntheses, structures, and magnetic properties of
          a family of end-on azido-bridged CuII–LnIII    complexes, Dalton Trans. 2017, 46, 7232.

  14.  Dong Shao,† Shao-Liang Zhang,† Le Shi,† Yi-Quan Zhang,*,‡ and Xin-Yi Wang*,†  Probing the Effect of Axial Ligands on Easy-Plane Anisotropy of      Pentagonal-Bipyramidal Cobalt(II) Single-Ion Magnets, Inorg. Chem. 2016, 55, 10859.

  15.  Rong-Min Wei1,2, Fan Cao1, Jing Li1, LiYang1, Yuan Han1, Xiu-Ling Zhang2, Zaichao Zhang3,      Xin-Yi Wang1 & You Song1,  Single-Chain Magnets Based on      Octacyanotungstate with the      Highest Energy Barriers for Cyanide      Compounds, Sci. Rep. 2016, 6, 24372.

  16.  Xiao-Qin Wei,†,‡ Kun Qian,† Hai-Yan Wei,*,‡ and Xin-Yi Wang*,†,  A One-Dimensional Magnet Based on [MoIII(CN)7]4−
           ,Inorg.Chem.2016, 55,5107.

  17. Jian Wang, Jia-Nan Li, Shao-Liang Zhang, Xin-Hua Zhao, Dong Shao and
          Xin-Yi Wang*,  Syntheses and magnetic properties of a pyrimidylsubstituted nitronyl nitroxide radical and its
        cobalt(II) complexes,Chem.Commun. 2016, 52, 5033.

  18. Dong Shao, Le Shi, Shao-Liang Zhang, Xin-Hua Zhao, Dong-Qing Wu,      Xiao-Qin Wei and Xin-Yi Wang*,  Syntheses, structures, and magnetic properties of      three new chain compounds based on a      pentagonal bipyramidal Co?II) building block,CrystEngComm 2016, 18, 4150.

  19. Xing-Cai Huang,a,b Ming Zhang,a Dayu Wu,*a Dong Shao,b Xin-Hua Zhao,b      Wei Huanga and Xin-Yi Wang*b,  Single molecule magnet behavior observed in a    1-D dysprosium chain with quasi-D5h symmetry,Dalton Trans.2015, 44,20134.

  20. Xin-Hua Zhao, Shao-Liang Zhang, Dong Shao, and Xin-Yi Wang*,  Spin Crossover in [Fe(2-Picolylamine)3]2+ Adjusted by      Organosulfonate Anions,Inorg. Chem.2015,54,7857.

  21. Dong Shao, Xin-Hua Zhao, Shao-Liang Zhang, Dong-Qing Wu, Xiao-Qin Wei and       Xin-Yi Wang*,Structural and magnetic tuning from a      field-induced single-ion magnet to a single-chain      magnet by anions, Inorg. Chem. Front. 2015, 2, 846.

  22. Xing-Cai Huang, Veacheslav Vieru,Liviu F. Chibotaru,* Wolfgang Wernsdorfer,Shang-Da Jiang* and Xin-Yi Wang*,Determination of magnetic anisotropy in a      multinuclear TbIII-based single-molecule magnet, Chem.Commun. 2015, 51, 10373.

  23. Shao-Liang Zhang, Xin-Hua Zhao and Xin-Yi Wang*,Syntheses, structures, and magnetic properties of       three new cyano-bridged complexes based on the    [Mn(CN)6]3? building block, Dalton Trans. 2015, DOI:10.1039/c5dt00038f.

  24. Shao-Liang Zhang, Xin-Hua Zhao, Yuan-Min Wang, Dong Shao and Xin-Yi Wang*,Spin crossover behaviour in one-dimensional      FeII compounds based on the [M(CN)4]2?    (M = Pd, Pt) units, Dalton Trans. 2015, 44, 9682-9690.

  25. Dong Shao, Shao-Liang Zhang, Xin-Hua Zhao and Xin-Yi Wang*, Spin canting, metamagnetism, and single-chain
          magnetic behaviour in a cyano-bridged homospin     iron(II) compound, Chem. Commun. 2015, 51, 4360-4363.(封面)

  26. Xing-Cai Huang, Chun Zhou, Dong Shao, Xin-Yi Wang*,Field-Induced Slow Magnetic Relaxation in Cobalt(II) Compounds       with Pentagonal Bipyramid Geometry, Inorg. Chem. 2014, 53, 12671-12673.

  27. Xin-Hua Zhao, Xing-Cai  Huang, Shao-Liang Zhang, Dong Shao, Hai-Yan Wei*, Xin-Yi Wang*, Cation-Dependent Magnetic Ordering and  Room-Temperature Bistability in Azido-Bridged Perovskite-Type Compounds, J. Am. Chem. Soc.2013, 135(43),  16006-16009.

  28. Kun, Qian, Xing-Cai Huang, Chun Zhou,  Xiao-Zeng You, Xin-Yi Wang*, Kim R  Dunbar*, A single-molecule magnet based on heptacyanomolybdate with the highest  energy barrier for a cyanide compound, J.  Am. Chem. Soc.2013, 135(36), 13302-13305.

  29. Xing-Cai Huang, Chun Zhou, Hai-Yai Wei*, Xin-Yi Wang*, End-on Azido-Bridged  3d-4f Complexes Showing Single-Molecule-Magnet Property, Inorg. Chem., 2013, 52(13), 7314- 7316.

  30. Bing-Wu Wang,Xin-Yi Wang, Hao-Ling Sun, Shang-Da  Jiang, Song Gao*,  Evolvement of  molecular nanomagnets in China, Phil. Trans. R. Soc. A, 2013, 371,200020120316 .

  31. Xiong, K. C.; Jiang, F. L.; Gai, Y. L; Zhou, Y. F.; Yuan,  D. Q.; Su, K. Z.; Wang, X. Y.*; Hong, M. C.*, 'A Series of  Octanuclear-Nickel(II) Complexes Supported by Thiacalix[4]arenes', Inorg. Chem. 2012, 51, 3283.
    Abstract Image

  32. Kecai Xiong, Xinyi Wang, Feilong Jiang, Yanli Gai,  Wentao Xu, Kongzhao Su, Xingjun Li, Daqiang Yuan, Maochun Hong*,  “Heterometallic thiacalix[4]arene-supported Na2NiII12LnIII2  clusters with vertex-fused tricubane cores (Ln = Dy and Tb)”, Chem. Commun.2012, 48, 7456–7458.
    Graphical abstract:Heterometallic thiacalix[4]arene-supported Na2NiII12LnIII2 clusters with vertex-fused tricubane cores (Ln = Dy and Tb)

  33. Wang X. Y.*, Wang, Z. M.; Gao S.* 'Detailed magnetic  study on the formato-bridged MOFs with anion-tunable magnetic properties'  Sci.  China. B, 2012, 55, 1055-1063.

  34. Wang, X. Y.*; Avendano,  C.; Dunbar K. R.* “Molecular magnetic materials based on 4d and 5d transition  metals”, Chem. Soc. Rev.2011, 40, 3213-3238.

  35. Wang, X. Y.; Prosvirin, A.  V.; Dunbar K. R.* “A docosanuclear Mo8Mn14 cluster based  on [Mo(CN)7]4−”, Angew. Chem. Int. Ed.2010, 49, 5081-5084. (封面)

  36. Wang, X. Y.; Hilfiger, M. G.; Prosvirin.  A.V.; Dunbar, K. R.* “Trigonal bipyramidal magnetic molecules based on [MoIII(CN)6]3-”, Chem. Commun.2010, 4484.

  37. Wang,X. Y.; Wang, Z. M.; Gao, S.* “Detailed magnetic studies on Co(N3)2(4-acetylpyridine)2:  a weak-ferromagnet with a very big canting angle”, Inorg. Chem.2008, 47,  5720-5726.

  38. Wang, X. Y.; Sevov S. C.* “A series of guest-defined metal-complex/disulfonate  frameworks of hydrogen-bonded [Co(en)2(ox)]+ and  2,6-Naphtalenedisulfonate”, Cryst. Grow.  Des.2008, 8, 1265-1270.

  39. Wang, X. Y.; Sevov S. C.* “Synthesis, structures, and magnetic properties of  metal-coordination polymers with benzenepentacarboxylate linkers”, Inorg. Chem.2008, 47,  1037-1043.

  40. Wang,X. Y.; Wang, Z. M.; Gao, S.* “Constructing molecular magnetic  solids by employing three-atom ligands as bridges”, Chem. Commun, 2008, 281-294. (综述)

  41. Wang, X. Y.; Sevov S. C.* “Hydrogen-bonded host frameworks of cationic metal  complexes and anionic disulfonate linkers: effects of the guest molecules and  the charge of the metal complex”, Chem.  Mater. 2007, 19, 4906-4912.

  42. Wang, X. Y.; Scancella, M.; Sevov S. C.* “Studies of the mechanism of a  single-crystal-to-single-crystal reversible dehydration of a copper-carboxylate  framework”, Chem. Mater.2007, 19, 4506-4513.

  43. Wang, X. Y.; Sevov S. C.* “A manganese carboxylate with geometrically frustrated  magnetic layers of novel topology”, Chem.  Mater.2007, 19, 3763-3766.

  44. Wang, X. Y.; Justice, R.; Sevov S. C.* “Hydrogen-bonded metal-complex sulfonate  (MCS) inclusion compounds: effect of the guest molecule on the host framework”, Inorg. Chem. 2007, 46, 4626-4631.

  45. Wang,X. Y.; Wang, Z. M.; Gao, S.*  “A pillared layer MOF with anion-tunable magnetic properties and photochemical  [2+2] cycloaddition”, Chem. Commun. 2007,  1127-1129.

  46. Wang,X. Y.; Wang, L.; Wang, Z. M.; Gao, S.* “Solvent templated azido-bridged Co2+ layers: square,  honeycomb, and Kagomé”,J. Am. Chem. Soc.2006, 128, 674-675.

  47. Wang,X. Y.; Wang, L.; Wang, Z. M.; Su, G.; Gao, S.* “Coexistence of  Spin-Canting, Metamagnetism, and Spin-Flop in a (4, 4) layered Mn-Azide  Polymer”, Chem. Mater. 2005, 17, 6369-6380.

  48. Wang,X. Y.; Li, B. L.*; Zhu, X.; Gao, S.* “Extended networks of Co2+  and Mn2+ bridged by NCS-/N3- anion  and flexible long spacer: syntheses, structures and magnetic properties”, Eur. J. Inorg. Chem.2005, 16, 3277-3286.

  49. Wang,X. Y.; Wei, H.Y.; Wang, Z. M.; Gao, S.*; Chen, Z. D.* “Formate — the analogue of azide: structural  and magnetic properties of M(HCOO)2(4,4’-bpy)·nH2O (M = Mn, Co, Ni; n = 0, 5)”,  Inorg. Chem. 2005, 44, 572-583

  50. Wang X. Y.; Gan Lin; Zhang Shi-Wei; *Gao Song, Perovskite-like metal formates with  weak ferromagnetism and as precursors to amorphous materials, Inorg. Chem. 2004, 43, 4615-4625.

  51. Li, R. Y.; Wang, X. Y.; Liu, T.; Xu, H. B.; Zhao, F.; Wang, Z. M.; Gao, S.*  “Synthesis, structure, and magnetism of three azido-bridged Co2+  compounds with a flexible coligand 1,2-(tetrazole-1-yl)ethane”, Inorg. Chem. 2008, 47, 8134-8142.

  52. Li, B. L.*; Wang, X. Y.; Zhu, X.; Gao, S.; Zhang, Y. “Synthesis, crystal structure  and magnetic behavior of two cobalt coordination polymers with  1,2-bis(1,2,4-triazol-1-yl)ethane and dicyanamide”, Polyhedron, 2007, 26, 5219-5224.

  53. Liu, X. T.*; Wang, X. Y.; Zhang, W. X.; Cui, P.; Gao, S.* “Weak  Ferromagnetism and Dynamic Magnetic Behavior in Single End-to-End Azide-Bridged  Nickel(II) Chain”,Adv. Mater.2006, 18, 2852-2856.

  54. Li, X. J.; Wang, X. Y.;Gao, S.*; Cao, R.* ‘Two  three-dimensional metal-organic frameworks containing one-dimensional  hydroxyl/carboxylate mixing bridged metal chains: syntheses, crystal structures  and magnetic properties” Inorg.  Chem.  2006, 45, 1508-1516.

  55. Lv, Z. L.; Wang, X. Y.; Liu, Z. L.; Liao, F. H.; Gao, S.*; Xiong, R. G.; Ma, H. W.;  Zhang, D. Q.*; Zhu, D. B. “Tuning the magnetic behavior via  dehydration/hydration treatment of a new ferrimagnet with the composition of K0.2Mn1.4Cr(CN)6·6H2O” Inorg. Chem. 2006, 45, 999-1004.