2017

(56) L. Wang, J. Li, L. Zhang, Y. Fang, C. Chen, Y. Zhao, Y. Song, L. Deng, G. Tan,* X. Wang,* and P. P. Power*, Isolable Borane-Based Diradical and Triradical Fused by a Diamagnetic Transition Metal Ion,J. Am. Chem. Soc. 2017, DOI: 10.1021/jacs.7b10141.

(55) W. Wang, J. Li, L. Yin, Y. Zhao, Z. Ouyang, X. Wang,* Z. Wang,* Y. Song,* P. P. Power,* Half-Sandwich Metal Carbonyl Complexes as Precursors to Functional Materials: From a Near-Infrared Absorbing Dye to a Single-Molecule Magnet. J. Am. Chem. Soc. 2017, DOI: 10.1021/jacs.7b06795.

(54) G. Tan, J. Li, L. Zhang, C. Chen, Y. Zhao, X. Wang,* Y. Song,* Y. Zhang,* M. Driess,* The Charge Transfer Approach to Radicals of a Heavier Main-Group element. Angew. Chem. Int. Ed. 2017, DOI: 10.1002/anie.201707501.

(53) T. Li, H. Wei, Y. Fang, S. Chen, Z. Zhang, Y. Zhao, G. Tan,* X. Wang,* Elusive Antimony-Centered Radical Cations: Isolation, Characterizations and Crystal Structures. Angew. Chem. Int. Ed. 2017, 56, 632. DOI:10.1002/anie.201610334

(52) G. Tan, X. Wang,* Isolable Bis(triarylamine) Dications: Analogues of Thiele’s, Chichibabin’s, and Mu?ller’s Hydrocarbons” . Acc. Chem. Res., 2017, DOI: 10.1021/acs.accounts.7b00229.

(51) L. Wang, Y. Fang, H. Mao, Y. Qu, J. Zuo, Z. Zhang, G. Tan,* X. Wang,* An Isolable Diboron-Centered Diradical with a Triplet Ground State. Chem. Eur. J. 2017, 23, 6930.

(50) N. Yuan, W. Wang, Y. Fang, J. Zuo, Y. Zhao, G. Tan,* X. Wang,* Bis(boryl anion)-Substituted Pyrenes: Syntheses, Characterizations, and Crystal Structures. Organometallics, 2017, 36, 2498.

(49) W. Wang , L. Wang , S. Chen , W. Yang , Z. Zhang , X. Wang,* Air-Stable Diradical Dications with Ferromagnetic Interaction Ex-ceeding the Thermal Energy at Room Temperature: From a Monomer to a Dimer. SCI. CHINA. Chem. 2017,DOI:10.1007/s11426-017-9101-5.

(48) S. Zhang, X. Wang, Z. Zhang, W. Wang, S. Liu, Y. Sui, G.Tan,* X. Wang,* Putting Aniline Radical Cations in a Bottle. SCI. CHINA Chem. 2017, DOI: ?10.1007/s11426-017-9096-7.

(47) T. Li, H. Wei, Z. Zhang, Y. Zhao, Y. Sui, X. Wang,*One-dimensional alkylate-bridged Würster’s blue-based diradical dications. SCI. CHINA Chem. 2017, 60, 602.

2016

(46) T. Li, G. Tan, D. Shao, J. Li, Z. Zhang, Y. Song, Y. Sui, S. Chen, Y. Fang, X. Wang,* Magnetic Bistability in a Discrete Organic Radical, J. Am. Chem. Soc. 2016, 138, 10092-10095.

(45) G. Tan, S. Li, S. Chen, Y. Sui, Y. Zhao, X. Wang,* Isolable Diphosphorus-Centered Radical Anion and Diradical Dianion. J. Am. Chem. Soc. 2016, 138, 6735-6738.

(44) Y. Su, X. Wang, Z. Zhang, L. Wang, X. Wang,* Y. Song* and Philip P. Power,* Thermally Controlling the Singlet-Triplet Energy Gap of a Diradical in the Solid State. Chem. Sci. 2016, 7, 6514-6518.

(43) N. Yuan, W. Wang, Z. Wu, S. Chen, G. Tan, Y. Sui, X. Wang,* J. Jiang,* and P. P. Power.*A Boron-Centered Radical: Potassium-Crown Ether Stabilized Boryl Radical Anion. Chem. Commun. 2016, 52, 12714 - 12716.

 

(42) X. Zheng, Z. Zhang, G. Tan,* X. Wang,* An Aliphatic Solvent-Soluble Lithium Salt of the Perhalogenated Weakly Coordinating Anion [Al(OC(CCl3)(CF3)2)4]. Inorg. Chem. 2016, 55, 1008-1010.

           

 

2015
(41) X. Zheng, X. Wang, Z. Zhang, Y. Sui, X. Wang,* P. P. Power,* Access to Stable Metalloradicals with Unsupported and Isomeric Metal-Metal Hemi-Bonds. Angew. Chem. Int. Ed. 2015,54,9084–9087,VIP paper.

                                                               

(40) Y. Su, X. Wang, Y. Li, Y. Song, Y. Sui, X. Wang,* Nitrogen Analogues of Thiele’s Hydrocarbon:Closed-Shell vs Open-Shell in the Ground State. Angew. Chem. Int. Ed. 2015,54,1634 – 1637. 


                             
                                               
(39)N. Yuan, Z. Zhang, X. Wang, X. Wang,* Isolation and Crystal Structure of a Dithiophene Dication: Controlling Covalent Connection and Disconnction with Temperature and Phase. Chem. Commun. 2015,51
, 16714-16717.

(38)S. Li, X. Wang, Z. Zhang, Y. Zhao, X. Wang,* Isolation and Structural Characterization of a Ligand-Based Dimetallic Radical.Dalton Trans. 2015,44,19754-19757.



(37)
X. Wang, Z. Zhang, Y. Song, Y. Su, X. Wang,* Phenothiazine-based diradicaloids: isolation, characterization and crystal structures. Chem. Commun. 2015,51,11822-11825.


                                                         


(36) W. Wang,  X. Wang, Z. Zhang, N. Yuan, X. Wang,* The Long-Sought Seventeen-Electron Radical [(C6Me6)Cr(CO)3]+: Isolation, Crystal Structure and Substitution Reaction. Chem. Communs. 2015,
51, 8410-8413. Front Cover.
 


(35) X. Pan, X. Wang,* Z. Zhang, X. Wang,* Two Phosphaalkene Radical Cations with Inverse Spin Density Distributions. Dalton Transactions 2015,44
,15099-15102.


                  


                                  

2014

(34) S. Zhang, X. Wang, Y. Sui,* X. Wang,* Odd-Electron Bonded Sulfur Radical Cations: X-ray Structural Evidence of a Sulfur-Sulfur Three-Electron σ–Bond. J. Am. Chem. Soc. 2014, 136, 14666–14669.
                                             
                      Highlighted by C&E News (“When Three Electrons Are Not A Crowd”, Oct. 27, 2014)

         

(33) X.Pan, X. Wang, Y. Zhao, Y. Sui, and X. Wang,* A Crystalline Phosphaalkene Radical Anion. J. Am. Chem. Soc. 2014, 136, 9834-9837.

        

(32) S. Zhang, X. Wang, Y. Su, Y. Qiu, Z. Zhang, and X. Wang,* Isolation and Reversible Dimerization of a Selenium–Selenium Three–Electron σ–Bond, Nature Communications, 2014, 5, 4127.

         
    


(31) Y. Su, X. Zheng, X. Wang, X. Zhang, Y. Sui, and X. Wang,* Two Stable Phosphorus-Containing Four-Membered Ring Radical Cations with Inverse Spin Density Distributions, J. Am. Chem. Soc. 2014, 136, 6251-6254.

  
 

(30) Y. Su, X. Wang, X. Zheng, Z. Zhang, Y. Song, Y. Sui, Y. Li, and X. Wang,* Tuning Ground States of
Bis(triphenylamine)benzidine Dications by Substituent Effect: From a Closed-Shell Singlet to a Diradicaloid
with an Excited Triplet State, Angew. Chem. Int. Ed. 2014, 53, 2857- 2861.     


    

 

(29)F. Gao, F. Zhu, X. Wang, Y. Xu, X. Wang,* and J. Zuo,* Stabilizing Radical Cation and Dication of a Tetrathiafulvalene Derivative by a Weakly Coordinating Anion, Inorg. Chem. 2014, 53, 5321 – 5327.

                                                 



2013

(28) X. Zheng, X. Wang, Y. Qiu, Y. Li, C. Zhou, Y. Sui, Y. Li, J. Ma, and X. Wang*, One-Electron Oxidation of an Organic Molecule by B(C6F5)3; Isolation and Structures of Stable Non-para-substituted Triarylamine Cation Radical and Bis(triarylamine) Dication Diradicaloid, J. Am. Chem. Soc. 2013, 135, 14912 - 14915 .

                          

 

(27) X. Pan, Y. Su, X. Chen, Y. Zhao, Y. Li, J. Zuo, and X. Wang,*Stable Tetraaryldiphosphine Radical Cation and Dication, J. Am. Chem. Soc. 2013, 135, 5561 - 5564 .

       


(26) X. Pan, X. Chen, T. Li, Y. Li, and X. Wang,* Isolation and X-ray Crystal Structures of Triarylphosphine Radical Cations, J. Am. Chem. Soc. 2013, 135,3414 - 3417

             

 

(25) X. Chen, X. Wang, Z. Zhou, Y. Li, Y. Sui, J. Ma, X. Wang,* P. P. Power,*Reversible σ-Dimerizations of Persistent Organic Radical Cations, Angew. Chem. Int. Ed. 2013, 52, 589-592.
                                     
                                

(24) X. Chen, B. Ma, S. Chen, Y. Li, W. Huang, J. Ma, X. Wang,*Synthesis, Crystal Structure, and Physical Property of Sterically Unprotected Thiophene/Phenylene Co-Oligomer Radical Cations: A Conductive π-π Bonded Supermolecular meso-Helix, Chem. -Asian J. 2013, 8, 238-243.
                                                 
                                                  


(23). T. S. Cameron, A. Decken, I. Krossing, J. Passmore,* J. M. Rautiainen,* X. Wang, X. Zeng, Reactions of a Cyclodimethylsiloxane (Me2SiO)6 with Silver Salts of Weakly Coordinating Anions; Crystal Structures of
[Ag(Me2SiO)6][Al] ([Al] = [FAl{OC(CF3)3}3], [Al{OC(CF3)3}4]) and their comparison with
[Ag(18-Crown-6)]2[SbF6]2,Inorg. Chem. 2013, 52, 3113 - 3126 .

 

2012


(22) X. Chen, X. Wang, Y. Sui,Y. Li, J. Ma,* J. Zuo and X. Wang,* Synthesis,Characterization and Structures of a Persistent Aniline Radical Cation, Angew. Chem. Int. Ed. 2012, 51,11878-11881.








(21) X. Chen, B. Ma, X. Wang, S. Yao, L. Ni, Z. Zhou, Y. Li, W. Huang, J. Ma, J. Zuo* and X. Wang*, From Monomersto
π
-Stacks,from Nonconductive to Conductive. Syntheses, Characterization and Crystal Structures of Benzidine Radical Cations, Chem. - Eur. J, 2012,18,11828-11836

        

 


2011

(20) X. Wang,* P. P. Power,* Structural Characterization, Infrared Spectroscopy and Theoretical Calculations for      B(C6F5)3 Stabilized Benzene-Ammonia and Benzene-Water Complexes, Angew. Chem. Int. Ed. 2011,50,10965.

                                 
                                                                     

 

(19) D. Aris, J. Beck, A. Decken, I. Dionne, J. S. A. D. Gunne, W. Hoffbauer, T. Kochner, I. Krossing, J. Passmore,* E. Rivard, F. Steden, X. Wang, Metastable Se6 as a ligand for Ag+: from isolated molecular to polymeric 1D and 2D structures, Dalton Transitions, 2011, 40, 5865 – 5880. AUTHORS LISTED ALPHABETICALLY (作者按姓氏第一个英文字母顺序排列)。




2004-2010 Graduate and Post-Doctoral Publications:

(18) X. Wang, Y. Peng, M. M. Olmstaead, H. Hope, P. P. Power*. A ditetrylyne as a π donor:synthesis and characterization of [AgAr'GeGeAr']+SbF6- and [Ag2Ar'GeGe(F)Ar']+SbF6-(Ar'=C6H3-2,6(C6H3-2,6-Pri2)2), J. Am. Chem. Soc. 2010, 132, 13150 - 13151.

 
 
(17) X. Wang, Y. Peng, Z. Zhu, J. C. Fettinger, P. P. Power*, J. Guo, S. Nagase. Synthesis and characterization of two of the three isomer models of a germanium substituted bicyclo[2.2.0]hexane diradicaloid: stretching the Ge-Ge bond, Angew. Chem. Int. Ed. 2010, 49, 4593 - 4597.


(16) T. Summerscales, X. Wang, P. P. Power*. Cleavage of the Sn Sn Multiple Bond in a Distannyne by Cyclooctatetraene: Formation of the π-Bound Inverse Sandwich Complex [(Ar′Sn)2(μ2-η2:η3-cot)], Angew. Chem. Int. Ed. 2010, 49, 4788 – 47905.


(15) Y. Peng, X. Wang, J. C. Fettinger, P. P. Power,* Reversible complexation of? isocyanides by the distannyne Ar'SnSnAr' (Ar' = C6H3-2,6(C6H3-2,6-iPr2), Chem. Commun. 2010, 46, 943.


(14) W. Merrill, E. Rivard, JS DeRopp, X. Wang, B. Ellis, J. Fettinger, B. Wrackmeyer, P. P. Power, Synthesis and Characterization of the M(II) (M = Ge, Sn, or Pb) Phosphinidene Dimers {M(mu-PAr')}2(Ar' = C6H3-2, 6-(C6H3-2, 6-Pri2)2), Inorg. Chem. 2010, 49, 8481-8486. 

 

(13) X. Wang, Y. Peng, J. C. Fettinger, M. Olmstead, P . P. Power*. An unsymmetric oxo/imido
bridged germanium-centered singlet diradicaloid, J. Am. Chem. Soc. 2009, 131, 14164 – 14165.


(12) X. Wang, Z. Zhu, Y. Peng, H. Lei, J. C. Fettinger, P. P. Power*. Room-temperature reaction of carbon monoxide with a stable diarylgermylene,J. Am. Chem. Soc. 2009, 131, 6912 - 6913.


(11) X. Wang, C. Ni, Z. Zhu, J. C. Fettinger, P. P. Power,* N-H and N=C bond formation via germanium (III) diradicaloid intermediates and C-S Bond cleavage in reactions of the digermyne Ar'GeGeAr' (Ar' = C6H3-2, 6-(C6H3-2, 6-Pri2)2) with azides, Inorg. Chem. 2009, 48, 2464 - 2470.


(10) Z. Zhu, X. Wang, M. M. Olmstead, P. P. Power*. Synthesis and characterization of [Ar'GaC(Ph)CH]2 and K2[Ar'GaC(Ph)CH]2.OEt2: from digallene to digallacyclohexadiene to digallabenzene. Angew. Chem. Int. Ed. 2009, 48, 2027 - 2030.



(9) Z. Zhu, X. Wang, Y. Peng, H. Lei, J. C. Fettinger, E. Rivard, P. P. Power*. Addition of hydrogen or ammonia to a low-valent group 13 metal species at 25oC and 1 atmosphere, Angew. Chem. Int. Ed. 2009, 48, 2031 - 2034.



(8) Y. Peng, B. D. Ellis, X. Wang, J. C. Fettinger, P. P. Power*. Reversible sigma- complexation of ethylene by main group molecules under ambient conditions, Science, 2009, 325, 1668 - 1669.



(7) A. Decken, C. Knapp,* G. B. Nikiforov, J. Passmore*, J. M. Rautiainen, X. Wang, X. Zeng. Silver(I) complexes of the weakly coordinating solvents SO2 and CH2Cl2: Crystal structures, bonding, and energetics of [Ag(OSO)][Al{OC(CF3)3}4], [Ag(OSO)2/2][SbF6], and [Ag(CH2Cl2)2][SbF6], Chem. - Eur. J. 2009, 6504 - 6517. AUTHORS LISTED ALPHABETICALLY (作者按姓氏第一个英文字母顺序排列).

 

(6) Y. Peng, B. D. Ellis, X. Wang, P. P. Power*. Diarylstannylene activation of hydrogen or ammonia with arene elimination, J. Am. Chem. Soc. 2008, 130, 12268–12269.

 

(5) A. Decken(X-ray), J. Passmore*, X. Wang. Cyclic dimethylsiloxanes as pseudo crown ethers: Syntheses and characterization of Li(Me2SiO)5[Al{OC(CF3)3}4], Li(Me2SiO)6[Al{OC(CF3)3}4], and Li(Me2SiO)6[Al{OC(CF3)3Ph}4], Angew. Chem. Int. Ed. 2006, 45, 2773 - 2777. AUTHORS LISTED ALPHABETICALLY
(作者按姓氏第一个英文字母顺序排列)。

  

Highlighted in C&E News (April 10, 2006, P54) and Angew Chem. Int. Ed. ( 2007, 46, 4610 - 4613).


(4) A. Decken, F. A. LeBlanc, J. Passmore*, X. Wang, Cyclodimethylsiloxanes (Me2SiO)n (n = 3
- 6) ring transformations on reactions with AgSbF6; Crystal structure of Ag(Me2SiO)7SbF6, 
Eur. J. Inorg. Chem. 2006, 4033 - 4036. AUTHORS LISTED ALPHABETICALLY (作者按姓氏第一个英文字母顺序排列).



 
(
3) D. Aris, C. Knapp, J. Passmore, X. Wang, A detailed account of a convenient lab-scale preparation of AsF5 via direct fluorination of AsF3, J. Fluorine. Chem. 2005, 126, 1368 -1372. AUTHORS LISTED ALPHABETICALLY
(作者按姓氏第一个英文字母顺序排列).

 


 (2)
T. S. Cameron (X-ray), J. Passmore*, X. Wang. The preparation and X-ray crystal structure of (AgI2)n?nMF6 (M = Sb, As): Diiodine acting as a donor in the planar polymeric (AgI2+)n, Angew Chem. Int. Ed. 2004, 43, 1995 – 1998. AUTHORS LISTED ALPHABETICALLY (作者按姓氏第一个英文字母顺序排列).

  Selected as a textbook example:Housecroft & Sharpe,Inorg. Chem. 3rd ed,Pearson,2006,p542.

 

(1) D. Aris, J. Beck, A. Decken, I. Dionne, I. Krossing, J. Passmore, E. Rivard, F. Steden, X. Wang, The metastable partially positively charged Se-6 molecule: Preparation, characterisation and x-ray crystal structure of [(Ag2Se6)SO2][Sb(OTeF5)6]2, [Ag2Se6][AsF6]2 and [AgSe6][Ag2(SbF6)3], Phosphorus Sulfur and silicon and the related elements, 2004, 179, 859-863. AUTHORS LISTED ALPHABETICALLY (作者按姓氏第一个英文字母顺序排列)

                               


      

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