Publications
  • (18) X. Wang, Y. Peng, M. M. Olmstaead, H. Hope, P. P. Power*, A ditetrylyne as a π-Electron Donor: Synthesis and Characterization of [AgAr'GeGeAr']+SbF6− and [Ag2Ar'GeGe(F)Ar']+SbF6- (Ar'=C6H3-2,6(C6H3-2,6-Pri2)2), J. Am. Chem. Soc. 2010, 132, 13150 - 13151.

     

  • (17) X. Wang, Y. Peng, Z. Zhu, J. C. Fettinger, P. P. Power*, J. Guo, S. Nagase. Synthesis and characterization of two of the three isomer models of a germanium substituted bicyclo[2.2.0]hexane diradicaloid: stretching the Ge-Ge bond, Angew. Chem. Int. Ed. 2010, 49, 4593 - 4597.

     

  • (16) T. Summerscales, X. Wang, P. P. Power*, Cleavage of the Sn-Sn Multiple Bond in a Distannyne by Cyclooctatetraene: Formation of the π-Bound Inverse Sandwich Complex [(Ar′Sn)2(μ2-η2:η3-cot)], Angew. Chem. Int. Ed. 2010, 49, 4788–47905.

     

  • (15) Y. Peng, X. Wang, J. C. Fettinger, P. P. Power*, Reversible complexation of isocyanides by the distannyne Ar'SnSnAr' (Ar' = C6H3-2,6(C6H3-2,6-iPr2), Chem. Commun. 2010, 46, 943.

     

  • (14) W. Merrill, E. Rivard, JS DeRopp, X. Wang, B. Ellis, J. Fettinger, B. Wrackmeyer, P. P. Power, Synthesis and Characterization of the M(II) (M = Ge, Sn, or Pb) Phosphinidene Dimers {M(μ-PAr')}2(Ar' = C6H3-2, 6-(C6H3-2, 6-Pri2)2), Inorg. Chem. 2010, 49, 8481-8486.

     

  • (13) X. Wang, Y. Peng, J. C. Fettinger, M. Olmstead, P . P. Power*, An unsymmetric oxo/imido bridged germanium-centered singlet diradicaloid, J. Am. Chem. Soc. 2009, 131, 14164 – 14165.

     

  • (12) X. Wang, Z. Zhu, Y. Peng, H. Lei, J. C. Fettinger, P. P. Power*. Room-temperature reaction of carbon monoxide with a stable diarylgermylene, J. Am. Chem. Soc., 2009, 131, 6912 - 6913.

     

  • (11) X. Wang, C. Ni, Z. Zhu, J. C. Fettinger, P. P. Power,* N-H and N=C bond formation via germanium (III) diradicaloid intermediates and C-S Bond cleavage in reactions of the digermyne Ar'GeGeAr' (Ar' = C6H3-2, 6-(C6H3-2, 6-Pri2)2) with azides, Inorg. Chem., 2009, 48, 2464 - 2470.

     

  • (10) Z. Zhu, X. Wang, M. M. Olmstead, P. P. Power*, Synthesis and characterization of [Ar'GaC(Ph)CH]2 and K2[Ar'GaC(Ph)CH]2.OEt2: from digallene to digallacyclohexadiene to digallabenzene, Angew. Chem. Int. Ed. 2009, 48, 2027 - 2030.

     

  • (9) Z. Zhu, X. Wang, Y. Peng, H. Lei, J. C. Fettinger, E. Rivard, P. P. Power*, Addition of hydrogen or ammonia to a low-valent group 13 metal species at 25oC and 1 atmosphere, Angew. Chem. Int. Ed. 2009, 48, 2031 - 2034.

     

  • (8) Y. Peng, B. D. Ellis, X. Wang, J. C. Fettinger, P. P. Power*, Reversible Reactions of Ethylene with Distannynes Under Ambient Conditions, Science, 2009, 325, 1668 - 1669.

     

  • (7) A. Decken, C. Knapp,* G. B. Nikiforov, J. Passmore*, J. M. Rautiainen, X. Wang, X. Zeng. Silver(I) complexes of the weakly coordinating solvents SO2 and CH2Cl2: Crystal structures, bonding, and energetics of [Ag(OSO)][Al{OC(CF3)3}4], [Ag(OSO)2/2][SbF6], and [Ag(CH2Cl2)2][SbF6], Chem. - Eur. J. 2009, 6504 - 6517. AUTHORS LISTED ALPHABETICALLY (作者按姓氏第一个英文字母顺序排列).

     

  • (6) Y. Peng, B. D. Ellis, X. Wang, P. P. Power*, Diarylstannylene activation of hydrogen or ammonia with arene elimination, J. Am. Chem. Soc. 2008, 130, 12268–12269.

     

  • (5) A. Decken(X-ray), J. Passmore*, X. Wang. Cyclic dimethylsiloxanes as pseudo crown ethers: Syntheses and characterization of Li(Me2SiO)5[Al{OC(CF3)3}4], Li(Me2SiO)6[Al{OC(CF3)3}4], and Li(Me2SiO)6[Al{OC(CF3)3Ph}4], Angew. Chem. Int. Ed. 2006, 45, 2773 - 2777. AUTHORS LISTED ALPHABETICALLY (作者按姓氏第一个英文字母顺序排列)。
    Highlighted in C&E News (April 10, 2006, P54) and Angew Chem. Int. Ed. ( 2007, 46, 4610 - 4613).

     

  • (4) A. Decken, F. A. LeBlanc, J. Passmore*, X. Wang, Cyclodimethylsiloxanes (Me2SiO)n (n = 3 - 6) ring transformations on reactions with AgSbF6; Crystal structure of Ag(Me2SiO)7SbF6,  Eur. J. Inorg. Chem. 2006, 4033 - 4036. AUTHORS LISTED ALPHABETICALLY (作者按姓氏第一个英文字母顺序排列).

     

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