State Key laboratory of Coordination Chemistry

School of Chemistry and Chemical Engineering
Nanjing University

Tel: 862583621651



Copyright reserved(c) 2014, Xinyi Wang
  1. Xing-Cai Huang,* Zi-Yi Qi, Chen-Long Ji, Yi-Ming Guo, Shi-Chang Yan,Yi-Quan Zhang,* Dong Shao and Xin-Yi Wang*, High-Coordinate CoII and FeII compounds Constructed from an Asymmetric Tetradentetra Ligand Showing Slow Magnetic Relaxation Behavior, Dalton Trans. 2018, DOI: 10.1039/c8dt01829d

  2. Xiao-Qin Wei, Qian Pi, Fu-Xing Shen, Dong Shao, Hai-Yan Wei* and Xin-Yi Wang*,Syntheses, structures, and magnetic properties of three new MnII–[MoIII(CN)7]4− molecular magnets,Dalton Trans., 2018, DOI: 10.1039/c8dt01433g
  3. Zhao-Xin Xiao, Hao Miao, Dong Shao, Hai-Yan Wei,* Yi-Quan Zhang* and Xin-Yi Wang*£¬A family of lanthanide compounds with reduced nitronyl nitroxide diradical: syntheses, structures and magnetic properties£¬Dalton Trans., 2018, 47, 7925.
  4. Dong Shao, Le Shi, Hai-Yan Wei*, and Xin-Yi Wang*£¬Field-induced single-ion magnet behavior in two cobalt(II) coordination polymers with 2,4,6-tris(4-pyridyl)-1,3,5-triazine£¬ Inorganics£¬ 2017£¬ 5 90.
  5. Dong-Qing Wu, Dong Shao, Xiao-Qin Wei, Fu-Xing Shen, Le Shi, Yi-Quan Zhang* and Xin-Yi Wang*, Single-ion magnetism in seven-coordinate YbIII complexes with distorted D5h coordination geometry, Dalton Trans. 2017,46,9088.

  6. Dong Shao, Le Shi, Fu-Xing Shen and Xin-Yi Wang*, A cyano-bridged coordination nanotube showing field-induced slow magnetic relaxation, CrystEngComm 2017, 19£¬ 5707.

  7. Dong-Qing Wu,† Dong Shao,† Xiao-Qin Wei,† Fu-Xing Shen,† Le Shi,† David Kempe,‡ Yuan-Zhu Zhang,*,§ Kim R. Dunbar,*,‡ and Xin-Yi Wang*, Reversible On−Off Switching of a Single-Molecule Magnet via a
    Crystal-to-Crystal Chemical Transformation, J. Am. Chem. Soc. 2017, 139, 11714.

  8. Dong Shao,[a] Lin-Dan Deng,[a] Le Shi,[a] Dong-Qing Wu,[a] Xiao-Qin Wei,[a] Si-Run Yang,[a] and Xin-Yi Wang*,Slow Magnetic Relaxation and Spin-Crossover Behavior in a Bicomponent Ion-Pair Cobalt(II) Complex, Eur. J. Inorg. Chem. 2017, 3862.

  9. Xin-Hua Zhao, Lin-Dan Deng, Yan Zhou, Dong Shao, Dong-Qing Wu, Xiao-Qin Wei,and Xin-Yi Wang*, Slow Magnetic Relaxation in One-Dimensional Azido-Bridged CoII Complexes, Inorg. Chem. 2017, 56, 8058.

  10. Dong-Qing Wu,† David Kempe,‡ Yan Zhou,† Lin-Dan Deng,† Dong Shao,† Xiao-Qin Wei,† Le Shi,† Kim R. Dunbar,*,‡ and Xin-Yi Wang*, Three-Dimensional FeII−[MoIII(CN)7]4− Magnets with Ordering below 65 K and Distinct Topologies Induced by Cation Identity, Inorg. Chem. 2017, 56, 7182.

  11. Jian Wang,a Hao Miao,a Zhao-Xin Xiao,a Yan Zhou,a Lin-Dan Deng,a Yi-Quan Zhang*b and Xin-Yi Wang *a, Syntheses, structures and magnetic properties of the lanthanide complexes of the pyrimidylsubstituted nitronyl nitroxide radical, Dalton Trans. 2017, 46, 10452.

  12. Dong Shao, Yan Zhou, Qian Pi, Fu-Xing Shen, Si-Run Yang, Shao-Liang Zhang and Xin-Yi Wang*, Two-dimensional frameworks formed by pentagonal bipyramidal cobalt(II) ions and hexacyanometallates: antiferromagnetic ordering,
    metamagnetism and slow magnetic relaxation, Dalton Trans, 2017, 46, 9088.

  13. Xing-Cai Huang, Xin-Hua Zhao,Dong Shaoa and Xin-Yi Wang*£¬ Syntheses, structures, and magnetic properties of
    a family of end-on azido-bridged CuII–LnIII complexes£¬ Dalton Trans. 2017, 46, 7232.
  14. Dong Shao,† Shao-Liang Zhang,† Le Shi,† Yi-Quan Zhang,*,‡ and Xin-Yi Wang*,† Probing the Effect of Axial Ligands on Easy-Plane Anisotropy of Pentagonal-Bipyramidal Cobalt(II) Single-Ion Magnets, Inorg. Chem. 2016, 55, 10859.

  15. Rong-Min Wei1,2, Fan Cao1, Jing Li1, LiYang1, Yuan Han1, Xiu-Ling Zhang2, Zaichao Zhang3, Xin-Yi Wang1 & You Song1, Single-Chain Magnets Based on Octacyanotungstate with the Highest Energy Barriers for Cyanide Compounds, Sci. Rep. 2016, 6, 24372.

  16. Xiao-Qin Wei,†,‡ Kun Qian,† Hai-Yan Wei,*,‡ and Xin-Yi Wang*,†, A One-Dimensional Magnet Based on [MoIII(CN)7]4−
    ,Inorg.Chem.2016, 55,5107.

  17. Jian Wang, Jia-Nan Li, Shao-Liang Zhang, Xin-Hua Zhao, Dong Shao and
    Xin-Yi Wang*, Syntheses and magnetic properties of a pyrimidylsubstituted nitronyl nitroxide radical and its
    cobalt(II) complexes,Chem.Commun. 2016, 52, 5033.

  18. Dong Shao, Le Shi, Shao-Liang Zhang, Xin-Hua Zhao, Dong-Qing Wu, Xiao-Qin Wei and Xin-Yi Wang*, Syntheses, structures, and magnetic properties of three new chain compounds based on a pentagonal bipyramidal Co?II) building block,CrystEngComm 2016, 18, 4150.

  19. Xing-Cai Huang,a,b Ming Zhang,a Dayu Wu,*a Dong Shao,b Xin-Hua Zhao,b Wei Huanga and Xin-Yi Wang*b£¬ Single molecule magnet behavior observed in a 1-D dysprosium chain with quasi-D5h symmetry£¬Dalton Trans.2015, 44,20134.

  20. Xin-Hua Zhao, Shao-Liang Zhang, Dong Shao, and Xin-Yi Wang*£¬ Spin Crossover in [Fe(2-Picolylamine)3]2+ Adjusted by Organosulfonate Anions£¬Inorg. Chem.2015,54£¬7857.
  21. Dong Shao, Xin-Hua Zhao, Shao-Liang Zhang, Dong-Qing Wu, Xiao-Qin Wei and Xin-Yi Wang*,Structural and magnetic tuning from a field-induced single-ion magnet to a single-chain magnet by anions, Inorg. Chem. Front. 2015, 2£¬ 846.
  22. Xing-Cai Huang, Veacheslav Vieru,Liviu F. Chibotaru,* Wolfgang Wernsdorfer,Shang-Da Jiang* and Xin-Yi Wang*,Determination of magnetic anisotropy in a multinuclear TbIII-based single-molecule magnet, Chem.Commun. 2015, 51, 10373.
  23. Shao-Liang Zhang, Xin-Hua Zhao and Xin-Yi Wang*,Syntheses, structures, and magnetic properties of three new cyano-bridged complexes based on the [Mn(CN)6]3? building block, Dalton Trans. 2015, DOI:10.1039/c5dt00038f.
  24. Shao-Liang Zhang, Xin-Hua Zhao, Yuan-Min Wang, Dong Shao and Xin-Yi Wang*£¬Spin crossover behaviour in one-dimensional FeII compounds based on the [M(CN)4]2? (M = Pd, Pt) units, Dalton Trans. 2015, 44, 9682-9690.
  25. Dong Shao, Shao-Liang Zhang, Xin-Hua Zhao and Xin-Yi Wang*, Spin canting, metamagnetism, and single-chain
    magnetic behaviour in a cyano-bridged homospin iron(II) compound, Chem. Commun. 2015, 51, 4360-4363.(·âÃ棩

  26. Xing-Cai Huang, Chun Zhou, Dong Shao, Xin-Yi Wang*£¬Field-Induced Slow Magnetic Relaxation in Cobalt(II) Compounds with Pentagonal Bipyramid Geometry, Inorg. Chem. 2014, 53, 12671-12673.

  27. Xin-Hua Zhao, Xing-Cai Huang, Shao-Liang Zhang, Dong Shao, Hai-Yan Wei*, Xin-Yi Wang*, Cation-Dependent Magnetic Ordering and Room-Temperature Bistability in Azido-Bridged Perovskite-Type Compounds, J. Am. Chem. Soc. 2013, 135(43), 16006-16009.
  28. Kun, Qian, Xing-Cai Huang, Chun Zhou, Xiao-Zeng You, Xin-Yi Wang*, Kim R Dunbar*, A single-molecule magnet based on heptacyanomolybdate with the highest energy barrier for a cyanide compound, J. Am. Chem. Soc. 2013, 135(36), 13302-13305.
  29. Xing-Cai Huang, Chun Zhou, Hai-Yai Wei*, Xin-Yi Wang*, End-on Azido-Bridged 3d-4f Complexes Showing Single-Molecule-Magnet Property, Inorg. Chem., 2013, 52(13), 7314- 7316.
  30. Bing-Wu Wang,Xin-Yi Wang, Hao-Ling Sun, Shang-Da Jiang, Song Gao*,  Evolvement of molecular nanomagnets in China, Phil. Trans. R. Soc. A, 2013, 371,200020120316 .

  31. Xiong, K. C.; Jiang, F. L.; Gai, Y. L; Zhou, Y. F.; Yuan, D. Q.; Su, K. Z.; Wang, X. Y.*; Hong, M. C.*, "A Series of Octanuclear-Nickel(II) Complexes Supported by Thiacalix[4]arenes", Inorg. Chem. 2012, 51, 3283.
    Abstract Image
  32. Kecai Xiong, Xinyi Wang, Feilong Jiang, Yanli Gai, Wentao Xu, Kongzhao Su, Xingjun Li, Daqiang Yuan, Maochun Hong*, ¡°Heterometallic thiacalix[4]arene-supported Na2NiII12LnIII2 clusters with vertex-fused tricubane cores (Ln = Dy and Tb)¡±, Chem. Commun. 2012, 48, 7456¨C7458.
    Graphical abstract: Heterometallic thiacalix[4]arene-supported Na2NiII12LnIII2 clusters with vertex-fused tricubane cores (Ln = Dy and Tb)
  33. Wang X. Y.*, Wang, Z. M.; Gao S.* "Detailed magnetic study on the formato-bridged MOFs with anion-tunable magnetic properties"  Sci. China. B, 2012, 55, 1055-1063.
  34. Wang, X. Y.*; Avendano, C.; Dunbar K. R.* ¡°Molecular magnetic materials based on 4d and 5d transition metals¡±, Chem. Soc. Rev. 2011, 40, 3213-3238.
  35. Wang, X. Y.; Prosvirin, A. V.; Dunbar K. R.* ¡°A docosanuclear Mo8Mn14 cluster based on [Mo(CN)7]4−¡±, Angew. Chem. Int. Ed. 2010, 49, 5081-5084. (·âÃæ)
  36. Wang, X. Y.; Hilfiger, M. G.; Prosvirin. A.V.; Dunbar, K. R.* ¡°Trigonal bipyramidal magnetic molecules based on [MoIII(CN)6]3-¡±, Chem. Commun. 2010, 4484.
  37. Wang, X. Y.; Wang, Z. M.; Gao, S.* ¡°Detailed magnetic studies on Co(N3)2(4-acetylpyridine)2: a weak-ferromagnet with a very big canting angle¡±, Inorg. Chem. 2008, 47, 5720-5726.
  38. Wang, X. Y.; Sevov S. C.* ¡°A series of guest-defined metal-complex/disulfonate frameworks of hydrogen-bonded [Co(en)2(ox)]+ and 2,6-Naphtalenedisulfonate¡±, Cryst. Grow. Des. 2008, 8, 1265-1270.
  39. Wang, X. Y.; Sevov S. C.* ¡°Synthesis, structures, and magnetic properties of metal-coordination polymers with benzenepentacarboxylate linkers¡±, Inorg. Chem. 2008, 47, 1037-1043.
  40. Wang, X. Y.; Wang, Z. M.; Gao, S.* ¡°Constructing molecular magnetic solids by employing three-atom ligands as bridges¡±, Chem. Commun, 2008, 281-294. (×ÛÊö)
  41. Wang, X. Y.; Sevov S. C.* ¡°Hydrogen-bonded host frameworks of cationic metal complexes and anionic disulfonate linkers: effects of the guest molecules and the charge of the metal complex¡±, Chem. Mater. 2007, 19, 4906-4912.
  42. Wang, X. Y.; Scancella, M.; Sevov S. C.* ¡°Studies of the mechanism of a single-crystal-to-single-crystal reversible dehydration of a copper-carboxylate framework¡±, Chem. Mater. 2007, 19, 4506-4513.
  43. Wang, X. Y.; Sevov S. C.* ¡°A manganese carboxylate with geometrically frustrated magnetic layers of novel topology¡±, Chem. Mater. 2007, 19, 3763-3766.
  44. Wang, X. Y.; Justice, R.; Sevov S. C.* ¡°Hydrogen-bonded metal-complex sulfonate (MCS) inclusion compounds: effect of the guest molecule on the host framework¡±, Inorg. Chem. 2007, 46, 4626-4631.
  45. Wang, X. Y.; Wang, Z. M.; Gao, S.* ¡°A pillared layer MOF with anion-tunable magnetic properties and photochemical [2+2] cycloaddition¡±, Chem. Commun. 2007, 1127-1129.
  46. Wang, X. Y.; Wang, L.; Wang, Z. M.; Gao, S.* ¡°Solvent templated azido-bridged Co2+ layers: square, honeycomb, and Kagom¨¦¡±, J. Am. Chem. Soc. 2006, 128, 674-675.
  47. Wang, X. Y.; Wang, L.; Wang, Z. M.; Su, G.; Gao, S.* ¡°Coexistence of Spin-Canting, Metamagnetism, and Spin-Flop in a (4, 4) layered Mn-Azide Polymer¡±, Chem. Mater. 2005, 17, 6369-6380.
  48. Wang, X. Y.; Li, B. L.*; Zhu, X.; Gao, S.* ¡°Extended networks of Co2+ and Mn2+ bridged by NCS-/N3- anion and flexible long spacer: syntheses, structures and magnetic properties¡±, Eur. J. Inorg. Chem. 2005, 16, 3277-3286.
  49. Wang, X. Y.; Wei, H.Y.; Wang, Z. M.; Gao, S.*; Chen, Z. D.* ¡°Formate ¡ª the analogue of azide: structural and magnetic properties of M(HCOO)2(4,4¡¯-bpy)¡¤nH2O (M = Mn, Co, Ni; n = 0, 5)¡±,  Inorg. Chem. 2005, 44, 572-583
  50. Wang X. Y.; Gan Lin; Zhang Shi-Wei; *Gao Song, Perovskite-like metal formates with weak ferromagnetism and as precursors to amorphous materials, Inorg. Chem. 2004, 43, 4615-4625.
  51. Li, R. Y.; Wang, X. Y.; Liu, T.; Xu, H. B.; Zhao, F.; Wang, Z. M.; Gao, S.* ¡°Synthesis, structure, and magnetism of three azido-bridged Co2+ compounds with a flexible coligand 1,2-(tetrazole-1-yl)ethane¡±, Inorg. Chem. 2008, 47, 8134-8142.

  52. Li, B. L.*; Wang, X. Y.; Zhu, X.; Gao, S.; Zhang, Y. ¡°Synthesis, crystal structure and magnetic behavior of two cobalt coordination polymers with 1,2-bis(1,2,4-triazol-1-yl)ethane and dicyanamide¡±, Polyhedron, 2007, 26, 5219-5224.

  53. Liu, X. T.*; Wang, X. Y.; Zhang, W. X.; Cui, P.; Gao, S.* ¡°Weak Ferromagnetism and Dynamic Magnetic Behavior in Single End-to-End Azide-Bridged Nickel(II) Chain¡±, Adv. Mater. 2006, 18, 2852-2856.

  54. Li, X. J.; Wang, X. Y.; Gao, S.*; Cao, R.* ¡®Two three-dimensional metal-organic frameworks containing one-dimensional hydroxyl/carboxylate mixing bridged metal chains: syntheses, crystal structures and magnetic properties¡± Inorg. Chem.  2006, 45, 1508-1516.

  55. Lv, Z. L.; Wang, X. Y.; Liu, Z. L.; Liao, F. H.; Gao, S.*; Xiong, R. G.; Ma, H. W.; Zhang, D. Q.*; Zhu, D. B. ¡°Tuning the magnetic behavior via dehydration/hydration treatment of a new ferrimagnet with the composition of K0.2Mn1.4Cr(CN)6¡¤6H2O¡± Inorg. Chem. 2006, 45, 999-1004.
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