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Publications


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2017


38. Benjamin C. Giglio, Haiyang Fei, Mengzhe Wang, Hui Wang, Liu He,1 Huijuan Feng, Zhanhong Wu, Hongjian Lu,* Zibo Li* "Synthesis of 18F-5F-α-Methylated Tryptophan and Others: Construction of New Trp Based PET Agents" Theranostics, 2017, ASAP.

 

37. Bin Yang, Kantapat Chansaenpakb,, Hongmiao Wu, Lin Zhua, Mengzhe Wang, Zibo Li* and Hongjian Lu* “Silver-Promoted (Radio)fluorination of Unsaturated Carbamates via a Radical Process” Chem.Commun. 2017, DOI: 10.1039/C7CC01393K.

 


 

2016


36. Yanrong Li, Mengshi Wang, Wei Fan, Fen Qian, Guigen Li,* and Hongjian Lu* “Cobalt-Catalyzed Cross-  Dehydrogenative Coupling Reactions of (Benz)oxazoles with Ethers” J. Org. Chem., 2016, 81, 11743–11750.

 

36

 

35. Hongmiao Wu, Bin Yang, Lin Zhu, Ronghua Lu, Guigen Li,* and Hongjian Lu* “High-Valent Palladium-Promoted  Formal Wagner−Meerwein Rearrangement” Org. Lett. 2016, 18, 5804–5807.

 

35

 

34. Lizheng Yang, Hao Li, Haifei Zhang and Hongjian Lu* “Palladium-Catalyzed Intramolecular C–H Amination in Water”  Eur. J. Org. Chem. 2016, 10.1002/ejoc.201601043.

 

 

 

33. Hongjian Lu,*  Kai Lang,   Huiling Jiang,   Lukasz Wojtasb and   X. Peter Zhang* “Intramolecular 1,5-C(sp3)–H  radical amination via Co(II)-based metalloradical catalysis for five-membered cyclic sulfamides” Chem. Sci., 2016, 7,  6934-6939 .

 

33

 

32. Qun Li, Yanrong Li, Weipeng Hu, Renjian Hu, Guigen Li,* and Hongjian Lu* “Cobalt-Catalyzed C(sp2)-H Methylation by using Dicumyl Peroxide as both the Methylating Reagent and Hydrogen Acceptor” Chem. Eur. J. 2016, 22,12286–12289.

 

 

 

31. Haowei Zhang, Bing Yang, Zhen Yang, Hongjian Lu, and Guigen Li “Asymmetric Synthesis of Chiral α-Methyl-α,β- diamino Acid Derivatives via Group-Assisted Purification Chemistry Using N-Phosphonyl Imines and a Ni(II)-Complexed Alanine Schiff Base” J. Org. Chem., 2016, 81, 7654–7661.

 

30. Tao Zhang, Zhen Wang, Xuejiao Hu, Meng Yu, Tianning Deng, Guigen Li, and Hongjian Lu* “Cesium Carboxylate-Promoted Iridium Catalyzed C−H Amidation/Cyclization with 2,2,2-Trichloroethoxycarbonyl Azide“ J. Org. Chem. 2016, 81 (11), 4898–4905.

 

29. Md Ashif Ali, Xiayin Yao, Guigen Li, Hongjian Lu* “Rhodium-Catalyzed Selective Mono- and Diamination of Arenes with Single Directing Site “On Water”” Org. Lett. 2016, 18, 1386.

 

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28. Tao Zhang; Xuejiao Hu; Zhen Wang; TianTian Yang; Hao Sun; Guigen Li; Hongjian Lu* “Carboxylate-assisted Iridium-Catalyzed C−H Amination of Arenes with Biologically Relevant Alkyl Azides” Chem. Eur. J. 2016, 22,2920–2924.

 

 

 


 

2015


27. Monalisa Goswami, Volodymyr Lyaskovskyy, Sérgio R. Domingos, Wybren Jan Buma, Sander Woutersen, Oliver Troeppner, Ivana Ivanović-Burmazović, Hongjian Lu, Xin Cui, X. Peter Zhang, Edward J. Reijerse, Serena DeBeer, Matti M. van Schooneveld, Florian Felix Pfaff, Kallol Ray, and Bas de Bruin “Characterization of Porphyrin-Co(III)-‘Nitrene Radical’ Species Relevant in Catalytic Nitrene Transfer Reactions” J. Am. Chem. Soc., 2015, 137, 5468–5479.

 

27

 

 

26. Ke Yang, Xinyong Chen, Yuqi Wang, Wanqing Li, Adnan A. Kadi, Hoong-Kun Fun, Hao Sun,* Yan Zhang, Guigen Li,* Hongjian Lu* “Cobalt-Catalyzed Decarboxylative 2-Benzoylation of Oxazoles and Thiazoles with α-Oxocarboxylic Acids”  J. Org. Chem., 2015, 80, 11065–11072.

 

26

 

25. Xiaodong Zou, Lizheng Yang, Xiangli Liu, Hao Sun, Hongjian Lu* "Silver Tetrafluoroborate-Catalysed Oxa-Diels-Alder Reaction Between Electrically Neutral Dienes and Aldehydes" Advanced Synthesis & Catalysis, 2015, DOI 10.1002/adsc.201500487.

 

 

 

24. Hongmiao Wu, Weiwei Zi, Guigen Li, Hongjian Lu,* F. Dean Toste* “Gold(I)-Catalyzed Desymmetrization of 1,4-Dienes by an Enantioselective Tandem Alkoxylation/Claisen Rearrangement” Angew. Chem. Int. Ed. 2015, 54, 8529.

 

23. Md Ashif Ali,§ Xiayin Yao,§ Hao Sun, Hongjian Lu* "[RhCp*Cl2]2 Catalyzed Directed N-Boc Amidation of Arenes “On Water”" Org. Lett. 2015, 17, 1513.

 

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22. Ke Yang, Yuqi Wang,Xinyong Chen, Adnan A. Kadi, Hoong-Kun Fun, Hao Sun, Yan Zhang, Hongjian Lu* “Nickel-Catalyzed and Benzoic Acid-Promoted Direct Sulfenylation of Unactivated Arenes” Chem. Comm., 2015, 51, 3582-3585.

 

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2014


21. Hongjian Lu,* Chaoqun Li, Huiling Jiang, Christopher L. Lizardi, Prof. Dr. X. Peter Zhang* “Chemoselective Amination of Propargylic C(sp3)-H Bonds by Cobalt(II)-Based Metalloradical Catalysis” Angew. Chem. Int. Ed. 2014, 53, 7028.

 

 

20. Ke Yang, Peng Wang, Cheng Zhang, Adnan A. Kadi, Hoong-Kun Fun, Yan Zhang,* Hongjian Lu* “Nickel-Catalyzed Decarboxylative Arylation of Heteroarenes through sp2 C–H Functionalization” Eur. J. Org. Chem. 2014, 34, 7586-7589.

 

 

19. Li-Mei Jin, Hongjian Lu, Yuan Cui, Christopher L. Lizardi, Thiago N. Arzua, Lukasz Wojtas, Xin Cui, X. Peter Zhang* “Selective radical amination of aldehydic C(sp2)–H bonds with fluoroaryl azides via Co(II)-based metalloradical catalysis: synthesis of N-fluoroaryl amides from aldehydes under neutral and nonoxidative conditions ”Chem. Sci. 2014. 5, 2422-2427.

 

 

 


 

Before 2013


18.Nanda D. Paul, M. Sc. Andrei Chirila, Hongjian Lu, X. Peter Zhang, Bas de Bruin* “Carbene Radicals in Cobalt(II)–Porphyrin-Catalysed Carbene Carbonylation Reactions; A Catalytic Approach to Ketenes”Chem.- Eur. J. 2013, 19, 12953.

 

 

17. Limei Jin, Xue Xu, Hongjian Lu, Xin Cui, Lukasz Wojtas, X. Peter Zhang* “Effective Synthesis of Chiral N-Fluoroaryl Aziridines through Enantioselective Aziridination of Alkenes with Fluoroaryl Azides”Angew. Chem. Int. Ed. 2013, 52, 5309.

16. Hongjian. Lu, Yang Hu, Huiling Jiang, Lukas Wojtas, X. Peter Zhang* “Stereoselective Radical Amination of Electron-Deficient C(sp3)–H Bonds by Co(II)-Based Metalloradical Catalysis: Direct Synthesis of α-Amino Acid Derivatives via α-C–H Amination” Org. Lett., 2012, 14, 5158-5161.

 

 

15. Hongjian Lu, Wojciech I. Dzik, Xue Xu, Lukasz Wojtas, Bas de Bruin,* X. Peter Zhang* “Experimental Evidence for Cobalt(III)-Carbene Radicals: Key Intermediates in Cobalt(II)-Based Metalloradical Cyclopropanation” J. Am. Chem. Soc. 2011, 133, 8518-8521.

 

 

14. Hongjian Lu, X. Peter Zhang* “Catalytic C–H Functionalization by Metalloporphyrins: Recent Developments and Future Directions” Chem. Soc. Rev. 2011, 40, 1899-1909.

 

 

13. Hongjian Lu, Huiling Jiang, Yang Hu, Lukasz Wojtas, X. Peter Zhang* “Chemoselective Intramolecular Allylic C-H Amination versus C=C Aziridination through Co(II)-Based Metalloradical Catalysis” Chem. Sci. 2011, 2, 2361 - 2366.

 

 

12. Xue Xu, Hongjian Lu, Joshua V. Ruppel, Xin Cui, Silke Lopez de Mesa, Lukasz Wojtas, X. Peter Zhang* “Highly Asymmetric Intramolecular Cyclopropanation of Acceptor-Substituted Diazoacetates by Co(II)-Based Metalloradical Catalysis: Iterative Approach for Development of New-Generation Catalysts” J. Am. Chem. Soc. 2011, 133 (39), 15292–15295.

 

 

11.Volodymyr Lyaskovskyy, Alma I. Olivos Suarez, Hongjian Lu, Huiling Jiang, X. Peter Zhang,* Bas de Bruin* “Mechanism of Cobalt(II) Porphyrin-Catalyzed C−H Amination with Organic Azides: Radical Nature and H-Atom Abstraction Ability of the Key Cobalt(III)-Nitrene Intermediates” J. Am. Chem. Soc. 2011, 133, 12264–12273.

 

 

10. Xin Cui, Xue Xu, Hongjian Lu, Shifa Zhu, Lukasz Wojtas, X. Peter Zhang* "Enantioselective Cyclopropenation of Alkynes with Acceptor/Acceptor-Substituted Diazo Reagents via Co(II)-Based Metalloradical Catalysis"  J. Am. Chem. Soc. 2011, 133, 3304–3307.

 

 

9. Hongjian Lu, Huiling Jiang, Lukasz Wojtas, X. Peter Zhang* “Selective Intramolecular C-H Amination through the Metalloradical Activation of Azides: Synthesis of 1,3-Diamines under Neutral and Nonoxidative Conditions” Angew. Chem. Int. Ed. 2010, 49, 10192-10196.

 

 

8. Hongjian Lu, Jingran Tao, Jess E. Jones, Lukasz Wojtas and X. Peter Zhang* “Co(II)-Catalyzed Intramolecular C–H Amination of Phosphoryl Azides: Formation of 6- and 7-Membered Cyclophosphoramidates” Org. Lett. 2010, 12, 1248–1251.

 

 

7. Hongjian Lu, Velusamy Subbarayan, Jingran Tao and X. Peter Zhang*  “Cobalt(II)-Catalyzed Intermolecular Benzylic C–H Amination with 2,2,2-Trichloroethoxycarbonyl Azide (TrocN3)” Organometallics. 2010, 29, 389–393.

 

 

6. Shifa Zhu, Joshua V. Ruppel, Hongjian Lu, Lukasz Wojtas and X. Peter Zhang* “Cobalt-Catalyzed Asymmetric Cyclopropanation with Diazosulfones: Rigidification and Polarization of Ligand Chiral Environment via Hydrogen Bonding and Cyclization” J. Am. Chem. Soc. 2008, 130, 5042-5043.

 

 

5. Hongjian Lu, Xinting Yuan, Shana Zhu, Changhui Sun and Chaozhong Li*  “Copper-Catalyzed Intramolecular N-Vinylation of Sulfonamides: General and Efficient Synthesis of Heterocyclic Enamines and Macrolactams” J. Org. Chem. 2008, 73, 8665-8668.

 

 

4. Hongjian Lu, Qian Chen, Chaozhong Li* “Control of the Regioselectivity of Sulfonamidyl Radical Cyclization by Vinylic Halogen Substitution” J. Org. Chem. 2007, 72, 2564-2569.

 

 

3. Yuanjia Pan, Hongjian Lu, Yewen Fang, Xinqiang Fang, Liqun Chen, Junlu Qian, Junhua Wang, Chaozhong Li* “Synthesis of Pyrroles via Copper-Catalyzed Coupling of Amines with Bromoenones” Synthesis 2007, 8, 1242-1246.

 

 

2. Hongjian Lu, Chaozhong, Li* “General and Highly Efficient Synthesis of 2-Alkylideneazetidines and β-Lactams via Copper-Catalyzed Intramolecular N-Vinylation” Org. Lett. 2006, 8, 5365-5367.

 

 

1. Hongjian Lu, Chaozhong Li* “Facile Cyclization of Amidyl Radicals Generated from N-acyltriazenes” Tetrahedron Lett. 2005, 46, 5983-5985.

 

 

 


 


 

 

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